One　of　the　major　impediments　to　using　electroorganic　synthesis　is　the　need　for　large　amounts　of　a　supporting　electrolyte　to　ensure　the　passage　of　charge.　Frequently　this　causes　separation　and　waste　problems.　To　address　these　issues,　a　polymeric　ionic　liquid-Super　P　carbon　black　composite　has　been　formulated.　The　system　enables　electrolyses　to　be　performed　without　adding　an　additional　supporting　electrolyte,　and　its　efficient　recovery　and　reuse.　In　addition,　the　ability　of　the　composite　to　modify　the　electrode　surface　in　situ　leads　to　improved　kinetics.　A　practical　consequence　is　that　one　can　decrease　catalyst　loading　without　sacrificing　efficiency.