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Author:

Coll, M. (Coll, M..) | Guzman, R. (Guzman, R..) | Garces, P. (Garces, P..) | Gazquez, J. (Gazquez, J..) | Rouco, V. (Rouco, V..) | Palau, A. (Palau, A..) | Ye, S. (Ye, S..) | Magen, C. (Magen, C..) | Suo, H. (Suo, H..) | Castro, H. (Castro, H..) | Puig, T. (Puig, T..) | Obradors, X. (Obradors, X..)

Indexed by:

CPCI-S EI Scopus SCIE

Abstract:

We present a thorough study of the nucleation and growth processes of the solution-based YBa2Cu3O7-Ba2YTaO6 ( YBCO-BYTO) system, carried out with a view to controlling the characteristics of the BYTO phase to meet the requirements for specific power applications. Scanning transmission electron microscopy and x-ray diffraction have been used to characterize the BYTO nucleation and phase evolution during the YBCO-BYTO conversion. At high BYTO loads ( > 10 mol%), the nanoparticles tend to aggregate, resulting in much less efficiency for generating nanostrained areas in the YBCO matrix, and enhancement of the vortex pinning. Our experiments show that by modifying the nucleation kinetics and thermodynamics of the BYTO, the nucleation mode ( homogeneous versus heterogeneous), the particle size and the particle orientation can be controlled. We demonstrate that YBCO-BYTO nanocomposites with high concentration of nanoparticles can be prepared in such a way as to obtain small and randomly oriented nanoparticles (i.e. high incoherent interface), generating highly strained nanoareas in the YBCO, with enhancement in the vortex pinning. We have also observed that the incoherent interface is not the only parameter controlling the nanostrain. The Cu-O intergrowth characteristics must also be a key factor for controlling the nanostrain in future tuning of YBCO vortex pinning.

Keyword:

YBCO nanocomposite nanoparticle size chemical solution deposition pinning

Author Community:

  • [ 1 ] [Coll, M.]ICMAB CSIC, Inst Ciencia Mat Barcelona, E-08193 Barcelona, Spain
  • [ 2 ] [Guzman, R.]ICMAB CSIC, Inst Ciencia Mat Barcelona, E-08193 Barcelona, Spain
  • [ 3 ] [Garces, P.]ICMAB CSIC, Inst Ciencia Mat Barcelona, E-08193 Barcelona, Spain
  • [ 4 ] [Gazquez, J.]ICMAB CSIC, Inst Ciencia Mat Barcelona, E-08193 Barcelona, Spain
  • [ 5 ] [Rouco, V.]ICMAB CSIC, Inst Ciencia Mat Barcelona, E-08193 Barcelona, Spain
  • [ 6 ] [Palau, A.]ICMAB CSIC, Inst Ciencia Mat Barcelona, E-08193 Barcelona, Spain
  • [ 7 ] [Ye, S.]ICMAB CSIC, Inst Ciencia Mat Barcelona, E-08193 Barcelona, Spain
  • [ 8 ] [Puig, T.]ICMAB CSIC, Inst Ciencia Mat Barcelona, E-08193 Barcelona, Spain
  • [ 9 ] [Obradors, X.]ICMAB CSIC, Inst Ciencia Mat Barcelona, E-08193 Barcelona, Spain
  • [ 10 ] [Garces, P.]Univ Nacl Colombia, Bogota, Colombia
  • [ 11 ] [Castro, H.]Univ Nacl Colombia, Bogota, Colombia
  • [ 12 ] [Ye, S.]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 13 ] [Suo, H.]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 14 ] [Magen, C.]Univ Zaragoza, Inst Nanociencia Aragon, E-50018 Zaragoza, Spain

Reprint Author's Address:

  • [Coll, M.]ICMAB CSIC, Inst Ciencia Mat Barcelona, Campus UAB, E-08193 Barcelona, Spain

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Related Keywords:

Source :

SUPERCONDUCTOR SCIENCE & TECHNOLOGY

ISSN: 0953-2048

Year: 2014

Issue: 4

Volume: 27

3 . 6 0 0

JCR@2022

ESI Discipline: PHYSICS;

ESI HC Threshold:202

JCR Journal Grade:2

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 44

SCOPUS Cited Count: 48

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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