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Abstract:
制备了介孔分子筛MSU-1,γ-A12O3,AC(活性炭)和MgO负载的CrOx催化剂,并考察了其催化CO2氧化异丁烷脱氢制异丁烯反应性能.结果表明,各催化剂活性的顺序为:CrOx/MSU-1 >CrOx/A12O3> CrOx/AC> CrOJMgO.其中在CrOx/MSU-1催化剂上,异丁烷的转化率和异丁烯的收率分别为59.2%和39.5%.同时,利用N2吸附-脱附、X射线衍射、X射线光电子能谱和程序升温脱附对催化剂进行了表征.结果表明,载体的比表面积对相应催化剂的初始活性有一定的影响;当CrOx负载量较低时,以单层分散于载体上,且含有较多孤立状态Cr6+时催化剂的活性更高.另外,催化剂表面的弱酸性也会影响其活性;而碱性位的存在可提高催化剂稳定性.
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Source :
催化学报
ISSN: 0253-9837
Year: 2011
Issue: 8
Volume: 32
Page: 1424-1429
1 6 . 5 0 0
JCR@2022
ESI Discipline: CHEMISTRY;
JCR Journal Grade:2
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ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count: 17
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30 Days PV: 0
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