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Author:

Xu Hang (Xu Hang.) | Yue Ming (Yue Ming.) (Scholars:岳明) | Zhao Chuan (Zhao Chuan.) | Zhang Dongtao (Zhang Dongtao.) (Scholars:张东涛) | Zhang Jiuxing (Zhang Jiuxing.)

Indexed by:

EI Scopus SCIE CSCD

Abstract:

Bulk Mn1.2Fe0.8-P0.76Ge0.24 alloy was prepared by mechanical milling and subsequent spark plasma sintering technique. Effect of annealing on the structure and magneto-caloric properties of the alloy was investigated. XRD results show that both sintered and annealed samples possess a hexagonal Fe2P-type crystal structure. After annealing, ferromagnetic impurity Fe3Mn4Ge6, which exists in the sintered sample, was eliminated from the alloy. Furthermore, the lattice constants a and c change noticeably, leading to a decrease in c/a ratio, while the cell volume almost remains invariable. As a result, the Curie temperature of the alloy increases from 253 K to 298 K, but the maximum magnetic entropy change decreases from 37.5 to 11.7 J.kg.K-1 for 2 T magnetic field change. On the other hand, the thermal hysteresis of M-T curves around T-C upon heating and cooling is 14 and 8 K for the as-sintered and the annealed sample, respectively, showing evident change.

Keyword:

isothermal entropy change Mn1.2Fe0.8P0.76Ge0.24 thermal hysteresis lattice constants

Author Community:

  • [ 1 ] [Xu Hang]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Yue Ming]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Zhao Chuan]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Zhang Dongtao]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Zhang Jiuxing]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

Reprint Author's Address:

  • 岳明

    [Yue Ming]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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Source :

RARE METALS

ISSN: 1001-0521

Year: 2012

Issue: 4

Volume: 31

Page: 336-338

8 . 8 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 9

SCOPUS Cited Count: 9

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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