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Au/SnO2 catalysts were prepared by deposition-precipitation (DP), co-precipitation (CP) and typical wet impregnation methods (IM). M(M= Pt, Pd)-promoted Au/SnO2 catalysts were prepared by the DP method. The samples were characterized by X-ray diffraction (XRD), Brunaner-Emmett-Teller (BET) adsorption, transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) techniques. The results showed that compared with CP and IM, the DP method led to a fairly uniform dispersion of gold nanoparticles with diameters less than 5 nm and larger specific surfaces for the Au/SnO2 catalyst. The Au in Au/SnO2-DP was metallic (Au-0) while in Au/SnO2-CP and Au/SnO2-IM the Au consisted of a mixture of Au-0 and Au3+. The oxidation of carbon monoxide over the Au/SnO2-DP and M-promoted Au/SnO2-DP catalysts were investigated. We observed that the Pd- or Pt-doping of Au/SnO2-DP resulted in a significant increase in performance. We conclude that the different activities of the Au/SnO2 catalysts that were prepared using different preparation methods may be attributed to the size of the Au particles and the states of gold. A remarkable improvement in catalytic activity because of Pd or Pt doping was associated with strong interactions between Pd or Pt and Au.
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ACTA PHYSICO-CHIMICA SINICA
ISSN: 1000-6818
Year: 2011
Issue: 1
Volume: 27
Page: 169-176
1 0 . 9 0 0
JCR@2022
ESI Discipline: CHEMISTRY;
JCR Journal Grade:4
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 3
SCOPUS Cited Count: 7
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1