The　stimulated　Raman　scattering　(SRS)　and　luminescence　spectra　of　ZnWO4　crystals　were　investigated　using　532　nm　laser　excitation　at　room　temperature.　It　was　found　that　the　first　order　(558.7　nm)　and　second　order　(588.6　nm)　of　SRS　have　130　and　77　cm(-1)　line　widths　and　the　pump　threshold　at　558.7　nm　is　6.8　mJ.　The　luminescence　spectrum　of　ZnWO,　crystals　under　532　mn　laser　excitation　has　the　peculiarity　of　having　the　band　structure　composed　of　three-Gaussian　components.　The　photoluminescence　spectrum　shows　broadband　emission　from　400　nm　to　650　nm　peaked　about　472.0　nm,　which　is　attributed　to　the　radiative　transitions　between　tungsten　and　oxygen.