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Abstract:
Uniform doping has been recognized as an effective approach to improve the cycling performance of many layered cathodes. Herein, we propose non-uniform doping as a more effective approach to enhance the cycling stability of layered cathodesviathe precipitation strengthening mechanism. In this work, we investigate four doped (Cu, Ti, Mg, and Zn) P2-layered cathodes for sodium ion batteries and validate that cycling induced dopant segregation can substantially enhance the cyclability due to mitigation of bulk cracking. Our comprehensive analysis indicates that dopant evolution is quite diverse during electrochemical cycling, not only depending on the nature of each dopant but also the cycling conditions applied. The migration and segregation behaviors of inactive dopants demonstrate the complex dynamics within grain bulk during battery cycling, which also offers us chances to engineer the physicochemical properties of layered cathodes. Non-uniform doping opens a new avenue for designing battery materials with superior mechanical properties.
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JOURNAL OF MATERIALS CHEMISTRY A
ISSN: 2050-7488
Year: 2020
Issue: 32
Volume: 8
Page: 16690-16697
1 1 . 9 0 0
JCR@2022
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:169
Cited Count:
WoS CC Cited Count: 23
SCOPUS Cited Count: 25
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1