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Author:

Wang, Yifei (Wang, Yifei.) | Gao, Zhixiao (Gao, Zhixiao.) | Shang, Yaxin (Shang, Yaxin.) | Qi, Ziyuan (Qi, Ziyuan.) | Zhao, Wen (Zhao, Wen.) | Peng, Yongzhen (Peng, Yongzhen.) (Scholars:彭永臻)

Indexed by:

EI Scopus SCIE

Abstract:

Three multifunctional adsorbents of carbon-based metal-organic framework (MOF) derivatives have been successfully prepared by varying zeolitic imidazolate framework-8 (ZIF8) and multiwalled carbon nanotube (MWCNT) ratio. Thus-synthesized nanocomposites are adopted to simultaneously remove conventional phosphate and emerging organic contaminants (EOC). Among the three hybrids, ZIF8/CNT40 possessing Zn: -OH (CNT) similar to 1:2 harvests the largest contaminant removal efficiency. For the single system of phosphate, the maximum phosphate adsorption capacity of ZIF8/CNT40 reaches 188.5 mg g(-1), and maintaining removal percentage of 100% and >92% in wastewater containing phosphate of 0.98 mg L-1 and 5.93 mg L-1 at neutral condition, respectively. As for phosphate-EOC binary system, the presence of phosphate has no significantly adverse impact on EOC removal. Nevertheless, the removal efficiency of phosphate is impeded by the presence of EOC, and this adverse impact of acetaminophen (AAP) and/or triclosan (TCS) is highly likely to be more serious in the binary system of phosphate and TCS. Such negative influences tend to be relived for ZIF8/CNT40 harnessing better tolerance of structure. Furthermore, these experimental results have shown a good agreement with the theoretical calculation, suggesting ZIF8/CNT hybrids hold a significant prospect for phosphate and EOC sequestration in environmental wastewater with complex components to eliminate growing eutrophication and increasing concern of EOC.

Keyword:

DFT calculation ZIF8/CNT hybrid Competition adsorption EOC Phosphate

Author Community:

  • [ 1 ] [Wang, Yifei]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment, Key Lab Beijing Water Qual Sci & Water Environm R, Beijing 100124, Peoples R China
  • [ 2 ] [Shang, Yaxin]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment, Key Lab Beijing Water Qual Sci & Water Environm R, Beijing 100124, Peoples R China
  • [ 3 ] [Qi, Ziyuan]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment, Key Lab Beijing Water Qual Sci & Water Environm R, Beijing 100124, Peoples R China
  • [ 4 ] [Peng, Yongzhen]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment, Key Lab Beijing Water Qual Sci & Water Environm R, Beijing 100124, Peoples R China
  • [ 5 ] [Gao, Zhixiao]China Univ Petr East China, Sch Mat Sci & Engn, Qingdao 266580, Peoples R China
  • [ 6 ] [Zhao, Wen]China Univ Petr East China, Sch Mat Sci & Engn, Qingdao 266580, Peoples R China

Reprint Author's Address:

  • 彭永臻

    [Wang, Yifei]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment, Key Lab Beijing Water Qual Sci & Water Environm R, Beijing 100124, Peoples R China;;[Peng, Yongzhen]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment, Key Lab Beijing Water Qual Sci & Water Environm R, Beijing 100124, Peoples R China;;[Zhao, Wen]China Univ Petr East China, Sch Mat Sci & Engn, Qingdao 266580, Peoples R China

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Source :

CHEMICAL ENGINEERING JOURNAL

ISSN: 1385-8947

Year: 2021

Volume: 417

1 5 . 1 0 0

JCR@2022

ESI Discipline: ENGINEERING;

ESI HC Threshold:87

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count: 34

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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