Electrochemically Oxidative Coupling of S-H/S-H for S-S Bond Formation: A Facile Approach to Diacid-disulfides - Details

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Abstract：

A　green　electrochemical　method　of　preparing　diacid-disulfides　has　been　developed,　in　which　an　S-S　bond　is　formed　by　electrochemically　oxidative　coupling　of　S-H/S-H　employing　redox　active　NaI　as　mediator.　The　reactions　are　carried　out　in　a　simple　undivided　cell　under　constant　current　condition　at　room　temperature　and　complete　in　1.3　h　to　afford　a　series　of　diacid-disulfides　with　up　to　97　%　yields.

Keyword：

synthetic methods electrochemistry S-S bond formation halide ion as redox catalyst indirect electrolysis

Author Community：

[ 1 ] [Sun, Xue-Jie]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
[ 2 ] [Yang, Shang-Feng]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
[ 3 ] [Wang, Zhi-Tong]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
[ 4 ] [Liang, Sen]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
[ 5 ] [Tian, Hong-Yu]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
[ 6 ] [Yang, Shao-Xiang]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
[ 7 ] [Liu, Yong-Guo]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
[ 8 ] [Sun, Bao-Guo]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
[ 9 ] [Zeng, Cheng-Chu]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
[ 10 ] [Zeng, Cheng-Chu]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing 100124, Peoples R China

Reprint Author's Address：

[Liang, Sen]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China;;[Tian, Hong-Yu]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China

Email：

liangsen@btbu.edu.cn |
tianhy@btbu.edu.cn

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Source ：

CHEMISTRYSELECT

ISSN： 2365-6549

Year： 2020

Issue： 15

Volume： 5

Page： 4637-4641

2 . 1 0 0

JCR@2022

Cited Count：

WoS CC Cited Count： 6

SCOPUS Cited Count： 10

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 1

Affiliated Colleges：

环境与生命学部

环境与生命学部生命科学与生物工程学院

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