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Abstract:
Lattice expansion in hybrid halide perovskite directly affects its photoelectric properties and the stability of perovskite-based optoelectronic devices, which was certified also to closely connect with relevant inducing mechanisms. From the perspective of carrier relaxation dynamics and dielectric properties, we report the results employing ultrafast time-resolved transient and steady-state reflectivity technology to diagnose the lattice expansion occurring in bulk hybrid perovskite MAPbI(3) during continuous illumination and directly heating, respectively. Upon continuous illumination at a constant temperature, there were no evident structural changes in MAPbI(3), but in the condition of naturally temperature changes, the lattice expansion can be induced by continuous light illumination and is consistent with the effect of heat-inducted expansion. The present results are based on the physical mechanism that the change of the electronic structure caused by lattice expansion leads to the change of the dielectric properties in MAPbI(3) and sequentially to the change of light reflectivity.
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JOURNAL OF APPLIED PHYSICS
ISSN: 0021-8979
Year: 2022
Issue: 1
Volume: 132
3 . 2
JCR@2022
3 . 2 0 0
JCR@2022
ESI Discipline: PHYSICS;
ESI HC Threshold:41
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
SCOPUS Cited Count: 3
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
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