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Author:

Zhen, Cheng (Zhen, Cheng.) | Ma, Limin (Ma, Limin.) | Liu, Shuang (Liu, Shuang.) | Wang, Yishu (Wang, Yishu.) | Li, Dan (Li, Dan.) | Guo, Fu (Guo, Fu.) (Scholars:郭福)

Indexed by:

EI Scopus SCIE

Abstract:

Electroplating crystalline cobalt-phosphorus (Co-P, with 1 similar to 8 at.% P) is a potential interfacial layer for electronic packaging solder joints, however, the optimal content of P has been lack of systematic research. In this work, crystalline Co-P coatings with P contents of 2, 4 and 6 at.% (Co-2P, Co-4P, Co-6P) were prepared and then bonded with Sn-Ag solder to form Cu/Co-xP/Sn-Ag solder joints. Within aging at 180 degrees C for 120 h, the diffusion resistance and intermetallic ductility of crystalline Co-P coatings with different P contents were systematically studied. The microstructure, phase composition and mechanical properties of Co-Sn intermetallic compounds (IMCs) were comprehensively characterized using XRD, SEM, EBSD and nano-indentation techniques. The XRD results showed that the Co-P coatings were crystalline structure, with obvious sharp diffraction peaks of beta-Co. The Co-4P system exhibited the slowest IMCs growth rate and the best diffusion resistance was obtained in this system, and the kinetic analysis showed that the Co-Sn IMCs growth at the interface was controlled by interface reaction and volume diffusion. It was found that CoSn3 was generated in the three systems during the aging process, while CoSn4 and Co-Sn-P were generated only in Co-6P system. Compared with Ni-Sn, Co-Sn exhibited significantly lower IMCs hardness, so the brittle fracture tendency of Co-P solder joints was lower. With the increase of P content, the hardness of Co-Sn IMCs increased first and then decreased, ranging from 3.20 to 4.94 GPa, and the minimum value was noticed in the Co-6P system. Co-4P coating would be a promising barrier layer owing to its good diffusion resistance, Co-6P coating may be used in solder joints with high mechanical load owing to its lowest IMCs hardness, and the Co-2P coating can maintain a balance in anti-diffusion and mechanical properties.

Keyword:

Author Community:

  • [ 1 ] [Zhen, Cheng]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 2 ] [Ma, Limin]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 3 ] [Liu, Shuang]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 4 ] [Wang, Yishu]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 5 ] [Li, Dan]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 6 ] [Guo, Fu]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 7 ] [Zhen, Cheng]Beijing Univ Technol, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 8 ] [Ma, Limin]Beijing Univ Technol, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 9 ] [Liu, Shuang]Beijing Univ Technol, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 10 ] [Wang, Yishu]Beijing Univ Technol, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 11 ] [Li, Dan]Beijing Univ Technol, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 12 ] [Guo, Fu]Beijing Univ Technol, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 13 ] [Guo, Fu]Beijing Union Univ, Coll Robot, Beijing 100101, Peoples R China

Reprint Author's Address:

  • [Ma, Limin]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China;;[Guo, Fu]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China;;[Ma, Limin]Beijing Univ Technol, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China;;[Guo, Fu]Beijing Univ Technol, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China;;[Guo, Fu]Beijing Union Univ, Coll Robot, Beijing 100101, Peoples R China;;

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Source :

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS

ISSN: 0957-4522

Year: 2023

Issue: 4

Volume: 34

2 . 8 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:26

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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