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Author:

Liu, Yutong (Liu, Yutong.) | Zhang, Xuetao (Zhang, Xuetao.) | Cao, Yue (Cao, Yue.) | Han, Rui (Han, Rui.) | Li, Hui (Li, Hui.) | Zhao, Xiaohui (Zhao, Xiaohui.) | He, Wanli (He, Wanli.) | Yang, Zhou (Yang, Zhou.) | Wang, Dong (Wang, Dong.) | Cao, Hui (Cao, Hui.) | Wang, Huihui (Wang, Huihui.) | Zhou, Hui (Zhou, Hui.)

Indexed by:

EI Scopus SCIE

Abstract:

Through a simple and effective method for preparing broadband reflective liquid crystal films, the advantages of the three-layer system are expanded based on the two-layer system. The cholesteric liquid crystals form a prepolymerized layer after semi-curing. In the design of the top prepolymerization layer, there is less content of the chiral compound R5011, which results in the formation of cholesteric liquid crystal molecules with a larger pitch. Mainly by controlling the content of polymerizable monomers and UV-absorbing dyes in cholesteric liquid crystals (CLCs), a polymer network with density gradient distribution suitable for substance diffusion is formed, and the oleophobic substrate on one side of the low-density polymer network is more likely to be peeled off. In the design of the lowest prepolymerization layer, the content of R5011 is higher, which results in the formation of cholesteric liquid crystals with a larger pitch. One side substrate of two cholesteric liquid crystal cassettes is peeled off and merged into a new liquid crystal cassette whose left and right sides are stacked with septum pads (20 mu m), and the nematic liquid crystals are poured into the middle layer to form a three-layer integrated film. The polymer network of the polymer-stabilized cholesteric liquid crystals (PSCLCs) itself in the bilayer was used as a diffusion channel. Chiral compounds and UV-absorbing dyes were diffused from the cholesteric liquid crystal layer to the intermediate nematic liquid crystal layer by diffusion gradient method, resulting in liquid crystal films with arbitrary wavelength bands and ultrawide broadband reflection.

Keyword:

polymer network photoinduced diffuse R5011 broadband reflection UV-327

Author Community:

  • [ 1 ] [Liu, Yutong]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing, Peoples R China
  • [ 2 ] [Zhang, Xuetao]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing, Peoples R China
  • [ 3 ] [Cao, Yue]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing, Peoples R China
  • [ 4 ] [Han, Rui]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing, Peoples R China
  • [ 5 ] [Li, Hui]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing, Peoples R China
  • [ 6 ] [Zhao, Xiaohui]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing, Peoples R China
  • [ 7 ] [He, Wanli]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing, Peoples R China
  • [ 8 ] [Yang, Zhou]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing, Peoples R China
  • [ 9 ] [Wang, Dong]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing, Peoples R China
  • [ 10 ] [Cao, Hui]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing, Peoples R China
  • [ 11 ] [Wang, Huihui]Beijing Univ Technol, Key Lab Optoelect Technol, Minist Educ, Beijing, Peoples R China
  • [ 12 ] [Zhou, Hui]Hangzhou Debang NDT Tech CL Ltd, Hangzhou, Zhejiang, Peoples R China

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Source :

POLYMERS FOR ADVANCED TECHNOLOGIES

ISSN: 1042-7147

Year: 2023

Issue: 12

Volume: 34

Page: 3849-3858

3 . 4 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:20

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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