Plasmonic-WS2　hybrids　have　attracted　widespread　interest　for　plasmon　driven　catalytic　reactions.　In　this　work,　a　Ag　nanoparticles　(NPs)/WS2　hybrid　was　fabricated　by　utilizing　a　one-step　anodized　Al　template-assisted　vacuum　thermal　evaporation　technique　and　wet　transfer　method.　To　optimize　the　catalytic　performance,　the　morphological　evolution　and　corresponding　changes　in　the　catalytic　properties　of　the　Ag　NPs/WS2　hybrid　at　different　thermal　annealing　temperatures　were　investigated.　It　was　found　that　the　surface-enhanced　Raman　scattering　(SERS)　and　catalytic　activity　of　the　hybrid　were　optimized　by　tuning　the　annealing　temperature,　with　the　optimal　SERS　and　catalytic　properties　observed　at　290　degrees　C.　These　results　may　open　new　avenues　for　improving　the　efficiency　and　expanding　the　research　field　of　plasmon-driven　reactions.