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Author:

Li, Chuan (Li, Chuan.) | Han, Li (Han, Li.) | Li, Qi (Li, Qi.) | Leng, Guoyun (Leng, Guoyun.) | Lu, Haitao (Lu, Haitao.) | Xu, Rongyu (Xu, Rongyu.) | Du, Yanping (Du, Yanping.) | Wu, Yuting (Wu, Yuting.)

Indexed by:

EI Scopus SCIE

Abstract:

This work concerns the development of a nitrate salt based form-stable composite phase change material by cold sintering technology with the employment of diatomite as skeleton substance. Such fabrication strategy has never before been reported in the literature and we demonstrate for the first time the feasibility of salt-diatomite composite production through a cold sintering process by means of sodium hydroxide solution as sintering additive. The microstructural characteristics and development mechanism, chemical and physical compatibility, mechanical strength, phase change behaviour, thermal and shape stability of the composite are investigated to reveal the structure formation and densification mechanism of salt and diatomite. The results show that the composite could be sintered at a temperature of 180 degrees C, far lower than that required in the traditional hot sintering approach. Due to the congruent solubility of the salt and diatomite in aqueous alkali, a rigid and dense structure induced by a so-called dissolution-precipitation process could be generated in the composite, which provides solution to accommodate the salt, endowing the composite with splendid capacity to maintain the structure stability and restrain the liquid leakage over the phase change process. An excellent chemical and physical compatibility has been achieved between the salt and other components, and over 60 wt% salt could be encapsulated in the composite by which a melting temperature around 278 degrees C and an energy storage density over 650 kJ/kg at a temperature range of 50-600 degrees C are attained. The results also reveal that the composite exhibits preeminent mechanical strength and excellent thermal cycling performance. For a given cycling temperature range of 50-500 degrees C, a stable macroscopic shape with a compressive strength over 210 MPa could be achieved in the composite even after 100 times of thermal cycles.

Keyword:

Shape stabilization Cold sintering Thermal energy storage Diatomite Composite phase change material

Author Community:

  • [ 1 ] [Li, Chuan]Beijing Univ Technol, MOE Key Lab Enhanced Heat Transfer & Energy Conser, Beijing Key Lab Heat Transfer & Energy Convers, Beijing 100124, Peoples R China
  • [ 2 ] [Han, Li]Beijing Univ Technol, MOE Key Lab Enhanced Heat Transfer & Energy Conser, Beijing Key Lab Heat Transfer & Energy Convers, Beijing 100124, Peoples R China
  • [ 3 ] [Li, Qi]Beijing Univ Technol, MOE Key Lab Enhanced Heat Transfer & Energy Conser, Beijing Key Lab Heat Transfer & Energy Convers, Beijing 100124, Peoples R China
  • [ 4 ] [Leng, Guoyun]Beijing Univ Technol, MOE Key Lab Enhanced Heat Transfer & Energy Conser, Beijing Key Lab Heat Transfer & Energy Convers, Beijing 100124, Peoples R China
  • [ 5 ] [Lu, Haitao]Beijing Univ Technol, MOE Key Lab Enhanced Heat Transfer & Energy Conser, Beijing Key Lab Heat Transfer & Energy Convers, Beijing 100124, Peoples R China
  • [ 6 ] [Xu, Rongyu]Beijing Univ Technol, MOE Key Lab Enhanced Heat Transfer & Energy Conser, Beijing Key Lab Heat Transfer & Energy Convers, Beijing 100124, Peoples R China
  • [ 7 ] [Wu, Yuting]Beijing Univ Technol, MOE Key Lab Enhanced Heat Transfer & Energy Conser, Beijing Key Lab Heat Transfer & Energy Convers, Beijing 100124, Peoples R China
  • [ 8 ] [Du, Yanping]Univ Lancaster, Sch Engn, Lancaster LA1 4YW, England

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Source :

SOLAR ENERGY MATERIALS AND SOLAR CELLS

ISSN: 0927-0248

Year: 2024

Volume: 271

6 . 9 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 6

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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