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Author:

Liu, Yutong (Liu, Yutong.) | Yuan, Xinpei (Yuan, Xinpei.) | Xie, Mengqi (Xie, Mengqi.) | Liu, Zhidong (Liu, Zhidong.) | Zhao, Xiaohui (Zhao, Xiaohui.) | Cao, Hui (Cao, Hui.) | Wang, Huihui (Wang, Huihui.) | Yang, Zhou (Yang, Zhou.) | Wang, Dong (Wang, Dong.) | He, Wanli (He, Wanli.)

Indexed by:

EI Scopus SCIE

Abstract:

In this study, we propose a simpler method to fabricate single-layer polymer cholesteric films with reflective bandwidth over 1500 nm instead of the previous multilayer films. We add polymerizable chiral compounds and non-polymerizable chiral compounds with the same rotation direction into the liquid crystal mixing system. Due to the presence of photoinitiators and UV-absorbing dyes, when UV light irradiates the polymerization, the polymerizable monomers, including the polymerizable chiral compounds, are rapidly polymerized in the nearlight side, and the non-polymerizable monomers, including the non-polymerizable chiral compounds and partial monoacrylate monomers, do diffusion movement towards the far-light side, and after the anchoring action of the polymer network, the formation of the small-large-small pitch gradient distribution is realized, which results in the broadband reflection. In the paper, the effect of multiple factors on the reflection broadband of the film is explored, and the polymer-stabilized cholesteric liquid crystal (PSCLC) film with a reflection bandwidth of 1572 nm is successfully prepared, which is demonstrated to have many desirable properties, including thinness and flexibility. The flexible CLC films reported in this study are expected to be promising prospects for several applications such as shielding infrared devices, energy-efficient windows for automobiles, and modern building facades.

Keyword:

IR reflector Pitch gradient Broadband reflection Cholesteric liquid crystal polymer

Author Community:

  • [ 1 ] [Liu, Yutong]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
  • [ 2 ] [Yuan, Xinpei]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
  • [ 3 ] [Xie, Mengqi]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
  • [ 4 ] [Liu, Zhidong]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
  • [ 5 ] [Zhao, Xiaohui]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
  • [ 6 ] [Cao, Hui]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
  • [ 7 ] [Wang, Dong]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
  • [ 8 ] [He, Wanli]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
  • [ 9 ] [Wang, Huihui]Beijing Univ Technol, Key Lab Optoelect Technol, Minist Educ, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Cao, Hui]Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China;;[Wang, Huihui]Beijing Univ Technol, Key Lab Optoelect Technol, Minist Educ, Beijing 100124, Peoples R China;;

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Source :

JOURNAL OF MOLECULAR LIQUIDS

ISSN: 0167-7322

Year: 2024

Volume: 408

6 . 0 0 0

JCR@2022

Cited Count:

WoS CC Cited Count: 2

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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