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Author:

Tao, Jinxiong (Tao, Jinxiong.) | Lin, Hongxia (Lin, Hongxia.) | Deng, Jiguang (Deng, Jiguang.) | Liu, Yuxi (Liu, Yuxi.) | Jing, Lin (Jing, Lin.) | Hou, Zhiquan (Hou, Zhiquan.) | Wei, Lu (Wei, Lu.) | Wang, Zhiwei (Wang, Zhiwei.) | Dai, Hongxing (Dai, Hongxing.)

Indexed by:

EI Scopus SCIE

Abstract:

The long-standing contradiction between low-temperature activity and high-temperature stability is one of the difficulties in catalytic combustion of low-concentration methane. The traditional Pd-CeO2 catalyst system has been applied to the oxidation of methane with low concentrations. However, the problem of sintering at high temperatures still exists. In this work, we prepared the Pt-modified Pd-CeO2 nanowires (NW) sample (in which the actual Pt, Pd, and Ce contents were 0.12, 0.86, and 9.8 wt%, respectively) using the one-pot reverse-micelle emulsion method. It was found that Pt-Pd-CeO2NW@SiO2 showed the highest low-temperature catalytic activity at a space velocity of 20,000 mL/(g h) and the best water resistance and high-temperature stability in the combustion of methane. The T50 % and T90 % (the temperatures for achieving methane conversions of 50 and 90 %) were 298 and 342 degrees C, respectively, methane reaction rate at 270 degrees C was 0.49 mu mol/(gcat s), and turnover frequency (TOF) at 270 degrees C was 0.198 s-1 over Pt-Pd-CeO2NW@SiO2; whereas over Pd-CeO2NW@SiO2 (in which the actual Pd and Ce contents were 0.82 and 10.6 wt%, respectively), the T50 % and T90 % were 360 and 420 degrees C, respectively, methane reaction rate at 270 degrees C was 0.074 mu mol/(gcat s), and TOF at 270 degrees C was 0.032 s- 1. The introduction of the highly dispersed Pt to Pd-CeO2NW@SiO2 could effectively increase the PdOx sites of unsaturated coordination through the electron-donating interaction of the Pt with PdO, which played an important role in activating the C-H bonds in methane. In addition, the unique structure of encapsulation also rendered the Pt-Pd-CeO2NW@SiO2 sample to possess good water resistance and thermal stability in methane combustion. We are sure that the present work provides a possibility for developing the catalysts with stable catalytic and water-resistant performance at low and high temperatures in the combustion of methane.

Keyword:

Methane combustion Water resistance Ceria nanowire Platinum doping Supported palladium catalyst

Author Community:

  • [ 1 ] [Tao, Jinxiong]Beijing Univ Technol, Coll Mat Sci & Engn, Dept Chem Engn & Technol, Educ Minist China,Beijing Key Lab Green Catalysis, Beijing 100124, Peoples R China
  • [ 2 ] [Lin, Hongxia]Beijing Univ Technol, Coll Mat Sci & Engn, Dept Chem Engn & Technol, Educ Minist China,Beijing Key Lab Green Catalysis, Beijing 100124, Peoples R China
  • [ 3 ] [Deng, Jiguang]Beijing Univ Technol, Coll Mat Sci & Engn, Dept Chem Engn & Technol, Educ Minist China,Beijing Key Lab Green Catalysis, Beijing 100124, Peoples R China
  • [ 4 ] [Liu, Yuxi]Beijing Univ Technol, Coll Mat Sci & Engn, Dept Chem Engn & Technol, Educ Minist China,Beijing Key Lab Green Catalysis, Beijing 100124, Peoples R China
  • [ 5 ] [Jing, Lin]Beijing Univ Technol, Coll Mat Sci & Engn, Dept Chem Engn & Technol, Educ Minist China,Beijing Key Lab Green Catalysis, Beijing 100124, Peoples R China
  • [ 6 ] [Hou, Zhiquan]Beijing Univ Technol, Coll Mat Sci & Engn, Dept Chem Engn & Technol, Educ Minist China,Beijing Key Lab Green Catalysis, Beijing 100124, Peoples R China
  • [ 7 ] [Wei, Lu]Beijing Univ Technol, Coll Mat Sci & Engn, Dept Chem Engn & Technol, Educ Minist China,Beijing Key Lab Green Catalysis, Beijing 100124, Peoples R China
  • [ 8 ] [Wang, Zhiwei]Beijing Univ Technol, Coll Mat Sci & Engn, Dept Chem Engn & Technol, Educ Minist China,Beijing Key Lab Green Catalysis, Beijing 100124, Peoples R China
  • [ 9 ] [Dai, Hongxing]Beijing Univ Technol, Coll Mat Sci & Engn, Dept Chem Engn & Technol, Educ Minist China,Beijing Key Lab Green Catalysis, Beijing 100124, Peoples R China
  • [ 10 ] [Tao, Jinxiong]Beijing Univ Technol, Coll Environm Sci & Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 11 ] [Lin, Hongxia]Beijing Univ Technol, Coll Environm Sci & Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 12 ] [Deng, Jiguang]Beijing Univ Technol, Coll Environm Sci & Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 13 ] [Liu, Yuxi]Beijing Univ Technol, Coll Environm Sci & Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 14 ] [Jing, Lin]Beijing Univ Technol, Coll Environm Sci & Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 15 ] [Hou, Zhiquan]Beijing Univ Technol, Coll Environm Sci & Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 16 ] [Wei, Lu]Beijing Univ Technol, Coll Environm Sci & Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 17 ] [Wang, Zhiwei]Beijing Univ Technol, Coll Environm Sci & Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 18 ] [Dai, Hongxing]Beijing Univ Technol, Coll Environm Sci & Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Deng, Jiguang]Beijing Univ Technol, Coll Mat Sci & Engn, Dept Chem Engn & Technol, Educ Minist China,Beijing Key Lab Green Catalysis, Beijing 100124, Peoples R China;;[Dai, Hongxing]Beijing Univ Technol, Coll Mat Sci & Engn, Dept Chem Engn & Technol, Educ Minist China,Beijing Key Lab Green Catalysis, Beijing 100124, Peoples R China;;

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Source :

APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY

ISSN: 0926-3373

Year: 2024

Volume: 360

2 2 . 1 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 7

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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