Indexed by:
Abstract:
Photoredox-based C-H bond functionalization constitutes one of the most powerful and atom-economical approaches to organic syntheses. During this type of reaction, single electron transfer takes place between the photocatalyst (PC) and redox- active substrates. Electrosynthesis also involves electron transfer between substrates and electrodes. In this paper, we focus upon electrochemical cross-coupling of C(sp(2))-H with aryldiazonium salts and have developed an efficient electrochemical approach to the Minisci-type arylation reaction. The constant current paired electrosynthesis proceeds in a simple undivided cell without external supporting electrolyte, features a wide range of substrates and is easy to scale-up. These results demonstrate that photoredox-based cross-coupling of C(sp(2))-H with aryldiazonium salts can also proceed successfully under paired electrolysis conditions, thereby contributing to understanding of the parallels between photosynthesis and electrosynthesis.
Keyword:
Reprint Author's Address:
Email:
Source :
ADVANCED SYNTHESIS & CATALYSIS
ISSN: 1615-4150
Year: 2019
Issue: 22
Volume: 361
Page: 5170-5175
5 . 4 0 0
JCR@2022
ESI Discipline: CHEMISTRY;
ESI HC Threshold:166
JCR Journal Grade:1
Cited Count:
WoS CC Cited Count: 72
SCOPUS Cited Count: 74
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: