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Author:

Jiang, Yang-ye (Jiang, Yang-ye.) | Dou, Gui-yuan (Dou, Gui-yuan.) | Zhang, Luo-sha (Zhang, Luo-sha.) | Xu, Kun (Xu, Kun.) | Little, R. Daniel (Little, R. Daniel.) | Zeng, Cheng-chu (Zeng, Cheng-chu.) (Scholars:曾程初)

Indexed by:

Scopus SCIE

Abstract:

Photoredox-based C-H bond functionalization constitutes one of the most powerful and atom-economical approaches to organic syntheses. During this type of reaction, single electron transfer takes place between the photocatalyst (PC) and redox- active substrates. Electrosynthesis also involves electron transfer between substrates and electrodes. In this paper, we focus upon electrochemical cross-coupling of C(sp(2))-H with aryldiazonium salts and have developed an efficient electrochemical approach to the Minisci-type arylation reaction. The constant current paired electrosynthesis proceeds in a simple undivided cell without external supporting electrolyte, features a wide range of substrates and is easy to scale-up. These results demonstrate that photoredox-based cross-coupling of C(sp(2))-H with aryldiazonium salts can also proceed successfully under paired electrolysis conditions, thereby contributing to understanding of the parallels between photosynthesis and electrosynthesis.

Keyword:

photoredox-based reactions cross-coupling paired electrolysis aryldiazonium salts quinoxalin-2(1H)-ones

Author Community:

  • [ 1 ] [Jiang, Yang-ye]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing Key Lab Environm & Viral Oncol, Beijing 100124, Peoples R China
  • [ 2 ] [Dou, Gui-yuan]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing Key Lab Environm & Viral Oncol, Beijing 100124, Peoples R China
  • [ 3 ] [Zhang, Luo-sha]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing Key Lab Environm & Viral Oncol, Beijing 100124, Peoples R China
  • [ 4 ] [Xu, Kun]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing Key Lab Environm & Viral Oncol, Beijing 100124, Peoples R China
  • [ 5 ] [Zeng, Cheng-chu]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing Key Lab Environm & Viral Oncol, Beijing 100124, Peoples R China
  • [ 6 ] [Little, R. Daniel]Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

Reprint Author's Address:

  • 曾程初

    [Zeng, Cheng-chu]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing Key Lab Environm & Viral Oncol, Beijing 100124, Peoples R China

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Source :

ADVANCED SYNTHESIS & CATALYSIS

ISSN: 1615-4150

Year: 2019

Issue: 22

Volume: 361

Page: 5170-5175

5 . 4 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:166

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 72

SCOPUS Cited Count: 74

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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