• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
搜索

Author:

Zhang, LingXiao (Zhang, LingXiao.) | Zhang, LiJuan (Zhang, LiJuan.) | Xi, LiDeGe (Xi, LiDeGe.)

Indexed by:

Scopus SCIE

Abstract:

In the present work, graphite fluoride-platinum(CFx-Pt) composites synthesized via a novel and simple in situ method are discussed as very promising cathodes for primary lithium-ion batteries. The influence of platinum on the performance of CFx was investigated through X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, high-resolution transmission electron microscopy and electrochemical measurements. We found that the emergence of semi-ionic C-F bonds and the uniform dispersion of platinum on the surface of CFx during the modification process are the most important factors for improving the electrochemical performance of the cathode material. With the conductivity provided by the platinum, the CFx-Pt cathode achieved a higher discharge capacity and a higher rate capability compared with those of the pristine CFx cathode; the CFx-Pt cathode exhibited a discharge capacity of 600 mAh g(-1), an excellent power density of 8692 W kg(-1) at a current density of 5 C, and a plateau of 2.0 V. More importantly, as a kind of lubricant, CFx makes it difficult to uniformly disperse modifying materials across its surface. However, our method opens a new avenue for the better dispersion of modifying materials on the surface of CFx.

Keyword:

Author Community:

  • [ 1 ] [Zhang, LingXiao]Beijing Univ Technol, Sch Environm & Energy Engn, Dept Chem & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing, Peoples R China
  • [ 2 ] [Zhang, LiJuan]Beijing Univ Technol, Sch Environm & Energy Engn, Dept Chem & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing, Peoples R China
  • [ 3 ] [Xi, LiDeGe]Beijing Univ Technol, Sch Environm & Energy Engn, Dept Chem & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing, Peoples R China

Reprint Author's Address:

  • [Zhang, LiJuan]Beijing Univ Technol, Sch Environm & Energy Engn, Dept Chem & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing, Peoples R China

Show more details

Related Keywords:

Related Article:

Source :

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE

ISSN: 1452-3981

Year: 2019

Issue: 6

Volume: 14

Page: 5738-5747

1 . 5 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:166

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count: 11

SCOPUS Cited Count: 10

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

Online/Total:545/5425063
Address:BJUT Library(100 Pingleyuan,Chaoyang District,Beijing 100124, China Post Code:100124) Contact Us:010-67392185
Copyright:BJUT Library Technical Support:Beijing Aegean Software Co., Ltd.