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Author:

Zou, Lu-lu (Zou, Lu-lu.) | Chen, Xia (Chen, Xia.) | Wu, Yu-ting (Wu, Yu-ting.) (Scholars:吴玉庭) | Wang, Xin (Wang, Xin.) | Ma, Chong-fang (Ma, Chong-fang.)

Indexed by:

EI Scopus SCIE

Abstract:

Renewable energy has been rapidly developing because of the increasing severity of pollution and energy crises. In particular, solar thermal power generation technology has been attracting considerable attention globally due to its large scale, low unit cost, and environment-friendliness. Thus, it has been quickly progressing. The intermittence and instability of solar energy can be solved by combination of solar thermal power with heat storage technology. Mixed molten salts stand out as heat transfer and storage materials due to their wide temperature range, low vapor pressure, high heat capacity, low viscosity, and economical environmental protection. In the present study, a new kind of quaternary nitrate molten salt was presented. The salt was Hitec salt with Ca(NO3)(2) additive and has a low melting point, high decomposition point, and low cost. The thermo-physical properties of the proposed salt, such as melting point, decomposition point, crystallization point, specific heat, density, thermal conductivity, and thermal stability, were measured. Results showed that the melting, crystallization, and decomposition points of the Hitec salt with Ca(NO3)(2) additive were 83.1 degrees C, 163.1 degrees C, and 628.5 degrees C, respectively. The proper working temperature range of the new salt was 200-565 degrees C, which was wider than those of Hitec salt (200-450 degrees C) and solar salt (290-565 degrees C). The average specific heat and thermal conductivity of the Hitec salt with Ca(NO3)(2) additive were approximately 1.52 J/(g K) and 0.655 W/(m K), respectively, which showed better heat storage and heat transfer performance than did Hitec salt (1.40 J/(g K) specific heat, 0.350 W/(m K) thermal conductivity) and solar salt (1.50 J/(g K) specific heat, 0.520 W/(m K) thermal conductivity). An experimental study was conducted on the stability of mixed molten salts at 565 degrees C for 1200 h and 120 times for quenching/heating at 200-500 degrees C, and the Hitec salt with Ca(NO3)(2) additive exhibited good thermal stability.

Keyword:

Thermal stability Molten salt Concentrating solar power Thermophysical properties

Author Community:

  • [ 1 ] [Zou, Lu-lu]Beijing Univ Technol, Coll Environm & Energy Engn, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China
  • [ 2 ] [Chen, Xia]Beijing Univ Technol, Coll Environm & Energy Engn, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China
  • [ 3 ] [Wu, Yu-ting]Beijing Univ Technol, Coll Environm & Energy Engn, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China
  • [ 4 ] [Ma, Chong-fang]Beijing Univ Technol, Coll Environm & Energy Engn, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China
  • [ 5 ] [Zou, Lu-lu]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing Educ Commiss, Key Lab Heat Transfer & Energy Convers, Beijing 100124, Peoples R China
  • [ 6 ] [Chen, Xia]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing Educ Commiss, Key Lab Heat Transfer & Energy Convers, Beijing 100124, Peoples R China
  • [ 7 ] [Wu, Yu-ting]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing Educ Commiss, Key Lab Heat Transfer & Energy Convers, Beijing 100124, Peoples R China
  • [ 8 ] [Ma, Chong-fang]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing Educ Commiss, Key Lab Heat Transfer & Energy Convers, Beijing 100124, Peoples R China
  • [ 9 ] [Wang, Xin]Beijing Univ Technol, Coll Mech Engn & Appl Elect Technol, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Chen, Xia]Beijing Univ Technol, Coll Environm & Energy Engn, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China

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Source :

SOLAR ENERGY MATERIALS AND SOLAR CELLS

ISSN: 0927-0248

Year: 2019

Volume: 190

Page: 12-19

6 . 9 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:211

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 57

SCOPUS Cited Count: 55

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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