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Author:

Zhao, Xingtian (Zhao, Xingtian.) | Liu, Yuxi (Liu, Yuxi.) | Deng, Jiguang (Deng, Jiguang.) | Xu, Peng (Xu, Peng.) | Yang, Jun (Yang, Jun.) | Zhang, Kunfeng (Zhang, Kunfeng.) | Han, Zhuo (Han, Zhuo.) | Dai, Hongxing (Dai, Hongxing.) (Scholars:戴洪兴)

Indexed by:

Scopus SCIE

Abstract:

Mesoporous cubic PdxPt (x= 0.43-8.52) alloys with surface areas of 26-32 m(2)/g were synthesized using the KIT-6-templating method. Physicochemical properties of the materials were characterized by means of various techniques, and their catalytic activities were evaluated for methane combustion. It is found that the Pd and Pt were uniformly distributed in the PdxPt alloys. The addition of Pt to Pd exerted a significant effect on the redox property of Pd. The PdxPt alloys possessed a higher methane activation ability than the monometallic Pd. The oxidized Pd-Pt (i.e., PdO-PtO2) were more active than the metallic Pd-0-Pt-0. The Pd-2.41 Pt sample performed the best for methane combustion (T-10%, T-50%, and T-90% were 272, 303, and 322 degrees C at SV=100,000 mL/(gh); TOFpd, TOFpt, TOFpd+pt, and specific reaction rate at 280 degrees C were 0.85 x 10(-3) s(-1), 1.98 x 10(-3) s(-1), 0.59 x 10(-3) s(-1), and 4.46 mu mol(g(cat) s), respectively). The deactivation of the Pd-2,Pd-41 Pt sample induced by 2.5-5.0 vol% CO2 or H2O addition was reversible, but its deactivation due to 100 ppm SO2 introduction was irreversible. It is concluded that the excellent catalytic performance of the Pd-2,Pd-41 Pt sample was associated with its good mesoporous structure, Pd-Pt alloy and PdO-PtO2 coexistence, and good methane and oxygen activation ability. (C) 2017 Elsevier B.V. All rights reserved.

Keyword:

Methane activation ability Methane combustion PdO-PtO2 active site Mesoporous Pd-Pt alloy Redox property

Author Community:

  • [ 1 ] [Zhao, Xingtian]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control,Coll Envir, Lab Catalysis Chem & Nanosci,Dept Chem & Chem Eng, Beijing 100124, Peoples R China
  • [ 2 ] [Liu, Yuxi]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control,Coll Envir, Lab Catalysis Chem & Nanosci,Dept Chem & Chem Eng, Beijing 100124, Peoples R China
  • [ 3 ] [Deng, Jiguang]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control,Coll Envir, Lab Catalysis Chem & Nanosci,Dept Chem & Chem Eng, Beijing 100124, Peoples R China
  • [ 4 ] [Xu, Peng]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control,Coll Envir, Lab Catalysis Chem & Nanosci,Dept Chem & Chem Eng, Beijing 100124, Peoples R China
  • [ 5 ] [Yang, Jun]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control,Coll Envir, Lab Catalysis Chem & Nanosci,Dept Chem & Chem Eng, Beijing 100124, Peoples R China
  • [ 6 ] [Zhang, Kunfeng]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control,Coll Envir, Lab Catalysis Chem & Nanosci,Dept Chem & Chem Eng, Beijing 100124, Peoples R China
  • [ 7 ] [Han, Zhuo]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control,Coll Envir, Lab Catalysis Chem & Nanosci,Dept Chem & Chem Eng, Beijing 100124, Peoples R China
  • [ 8 ] [Dai, Hongxing]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control,Coll Envir, Lab Catalysis Chem & Nanosci,Dept Chem & Chem Eng, Beijing 100124, Peoples R China

Reprint Author's Address:

  • 邓积光

    [Liu, Yuxi]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control,Coll Envir, Lab Catalysis Chem & Nanosci,Dept Chem & Chem Eng, Beijing 100124, Peoples R China;;[Deng, Jiguang]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control,Coll Envir, Lab Catalysis Chem & Nanosci,Dept Chem & Chem Eng, Beijing 100124, Peoples R China

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Related Keywords:

Source :

MOLECULAR CATALYSIS

ISSN: 2468-8231

Year: 2017

Volume: 442

Page: 191-201

4 . 6 0 0

JCR@2022

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 21

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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