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Abstract:
The magnetocaloric properties of the as-consolidated nanocrystalline and coarse-grained gadolinium metals were studied in the present work. With the decrease of Gd grains from micrometer to nanometer range, magnetic entropy change drops surprising from 10.07 to 4.47 J kg −1 K −1 at a magnetic-field change of 5 T, and their resultant magnetic entropy change uniformly peaks at 294, 290, and 288 K, respectively, corresponding to the magnetic transition temperature of the three samples. The Curie temperature T C of the nanocrystalline Gd shifts by more than 6 K below that of coarse-grained Gd sample. However, the values of magnetic entropy change of the nanocrystalline metals exhibit a more constant tendency compared with the coarse-grained sample. The Arrott plots indicate the second-order character of magnetic phase transition still in the nanocrystalline Gd metals. The refrigerant capacity calculated is also used to evaluate material refrigeration capacity. © 2011, The Author(s).
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Applied Nanoscience (Switzerland)
ISSN: 2190-5509
Year: 2011
Issue: 1
Volume: 1
Page: 51-57
ESI Discipline: MATERIALS SCIENCE;
Cited Count:
WoS CC Cited Count: 0
SCOPUS Cited Count: 38
ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0