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Author:

Xu, Lei (Xu, Lei.) | Zhao, Jin-Liang (Zhao, Jin-Liang.) | Yang, Jing-Jie (Yang, Jing-Jie.) | Zhang, Hong-Guo (Zhang, Hong-Guo.) | Liu, Dan-Min (Liu, Dan-Min.) (Scholars:刘丹敏) | Yue, Ming (Yue, Ming.) (Scholars:岳明) | Jang, Yi-Jian (Jang, Yi-Jian.)

Indexed by:

EI Scopus SCIE CSCD

Abstract:

In this paper, we study the effects of Pr substitution on the hydrogenating process and magnetocaloric properties of La1-x PrxFe11.4Si1.6Hy hydrides. The powder x-ray diffraction patterns of the La1-x PrxFe11.4Si1.6 and its hydrides show that each of the alloys is crystallized into the single phase of cubic NaZn13-type structure. There are hydrogen-absorbing plateaus under 0.4938 MPa and 0.4882 MPa in the absorbing curves for the La-0.8 Pr0.2Fe11.4Si1.6 and La0.6Pr0.4Fe11.4Si1.6 compounds. The releasing processes lag behind the absorbing process, which is obviously different from the coincidence between absorbing and releasing curves of the LaFe11.4Si1.6 compound. The remnant hydrogen content for La0.6Pr0.4Fe11.4Si1.6 is significantly more than that for La0.8Pr0.2Fe11.4Si1.6 after hydrogen desorption, indicating that more substitutions of Pr for La are beneficial to retaining more hydrogen atoms in the alloys. The values of maximum magnetic entropy change are 14.91 J/kg center dot K and 17.995 J/kg center dot K for La0.8Pr0.2Fe11.4 si(1.6)H(0.13) and La0.6Pr0.4Fe11.4Si1.6 H-0.87, respectively.

Keyword:

magnetocaloric effect magnetic refrigeration materials hydrogenating process La(Fe,Si)(13) compounds

Author Community:

  • [ 1 ] [Xu, Lei]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Zhang, Hong-Guo]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Yue, Ming]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Xu, Lei]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China
  • [ 5 ] [Zhao, Jin-Liang]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China
  • [ 6 ] [Yang, Jing-Jie]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China
  • [ 7 ] [Liu, Dan-Min]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 8 ] [Jang, Yi-Jian]Beijing Univ Technol, Inst Laser Engn, Beijing 100124, Peoples R China

Reprint Author's Address:

  • 岳明

    [Yue, Ming]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China;;[Zhao, Jin-Liang]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China

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Source :

CHINESE PHYSICS B

ISSN: 1674-1056

Year: 2017

Issue: 6

Volume: 26

1 . 7 0 0

JCR@2022

ESI Discipline: PHYSICS;

ESI HC Threshold:158

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 7

SCOPUS Cited Count: 7

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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