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Author:

Zhang, Zhenhua (Zhang, Zhenhua.) | Guo, Hua (Guo, Hua.) | Ding, Wenqiang (Ding, Wenqiang.) | Zhang, Bin (Zhang, Bin.) | Lu, Yue (Lu, Yue.) (Scholars:卢岳) | Ke, Xiaoxing (Ke, Xiaoxing.) | Liu, Weiwei (Liu, Weiwei.) | Chen, Furong (Chen, Furong.) | Sui, Manling (Sui, Manling.) (Scholars:隋曼龄)

Indexed by:

EI Scopus SCIE PubMed

Abstract:

Controlling phase transition in functional materials at nano scale is not only of broad scientific interest but also important for practical applications in the fields of renewable energy, information storage, transducer, sensor, and so forth. As a model functional material, vanadium dioxide (VO2) has its metal insulator transition (MIT) usually at a sharp temperature around 68 degrees C. Here, we report a focused electron beam can directly lower down the transition temperature of a nanoarea to room temperature without prepatterning the VO2. This novel process is called radiolysis-assisted MIT (R-MIT). The electron beam irradiation fabricates a unique gradual MIT zone to several times of the beam size in which the temperature-dependent phase transition is achieved in an extended temperature range. The gradual transformation zone offers to precisely control the ratio of metal/insulator phases. This direct electron writing technique can open up an opportunity to precisely engineer nanodomains of diversified electronic properties in functional material-based devices.

Keyword:

oxygen vacancy domain wall transition temperature Vanadium dioxide (VO2) metal-insulator transition (MIT) radiolysis

Author Community:

  • [ 1 ] [Zhang, Zhenhua]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 2 ] [Ding, Wenqiang]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 3 ] [Zhang, Bin]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 4 ] [Lu, Yue]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 5 ] [Ke, Xiaoxing]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 6 ] [Sui, Manling]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 7 ] [Guo, Hua]Rice Univ, Dept Mat Sci & NanoEngn, Houston, TX 77005 USA
  • [ 8 ] [Chen, Furong]Natl Tsing Hua Univ, Dept Engn & Syst Sci, Hsinchu 300, Taiwan
  • [ 9 ] [Liu, Weiwei]Beijing Computat Sci Res Ctr, Beijing 100084, Peoples R China

Reprint Author's Address:

  • 隋曼龄

    [Sui, Manling]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China;;[Chen, Furong]Natl Tsing Hua Univ, Dept Engn & Syst Sci, Hsinchu 300, Taiwan

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Source :

NANO LETTERS

ISSN: 1530-6984

Year: 2017

Issue: 2

Volume: 17

Page: 851-855

1 0 . 8 0 0

JCR@2022

ESI Discipline: PHYSICS;

ESI HC Threshold:158

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 39

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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