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Exploring the mechanical and electronic properties of skeletal and blocky carbides in DZ125 superalloy through first-principles and experiments SCIE
期刊论文 | 2024 , 41 | MATERIALS TODAY COMMUNICATIONS
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Abstract :

The diverse shapes and multi-component characteristics of complex carbides in nickel-based superalloys play a crucial role in determining their mechanical properties. However, relying solely on experimental evaluations poses challenges, making analog simulations essential. This study investigates the structural, mechanical, and electronic properties of skeletal and blocky carbides in the DZ125 superalloy using first-principles calculation and experimental methods. The carbides analyzed include Ti0.125Ta0.625Hf0.25C and Ti0.125Ta0.25Hf0.625C, which differ in their Ta and Hf ratios. The results indicate that Ti0.125Ta0.625Hf0.25C exhibits superior mechanical properties compared to Ti0.125Ta0.25Hf0.625C, along with enhanced fracture toughness and higher energy requirements for crack propagation. Electronic characteristic analysis reveals that Ti0.125Ta0.625Hf0.25C possesses greater thermodynamic stability due to the presence of more valence electrons in Ta atoms, which form stronger covalent and metallic bonds. Additionally, quasi-in-situ tensile testing confirms that skeletal carbides exhibit higher cracking resistance compared to blocky carbides. This study enhances our understanding of the stability of these carbides and provides valuable insights for the design and optimization of DZ125 superalloys.

Keyword :

Carbides Carbides Electronic properties Electronic properties First-principles calculations First-principles calculations Mechanical properties Mechanical properties

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GB/T 7714 Wang, Qin , Liu, Furong , Song, Jinxia et al. Exploring the mechanical and electronic properties of skeletal and blocky carbides in DZ125 superalloy through first-principles and experiments [J]. | MATERIALS TODAY COMMUNICATIONS , 2024 , 41 .
MLA Wang, Qin et al. "Exploring the mechanical and electronic properties of skeletal and blocky carbides in DZ125 superalloy through first-principles and experiments" . | MATERIALS TODAY COMMUNICATIONS 41 (2024) .
APA Wang, Qin , Liu, Furong , Song, Jinxia , Kang, Yongwang , Wu, Yuhong , Wang, Dinggang et al. Exploring the mechanical and electronic properties of skeletal and blocky carbides in DZ125 superalloy through first-principles and experiments . | MATERIALS TODAY COMMUNICATIONS , 2024 , 41 .
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一种硫系相变材料结合Ag纳米颗粒多层薄膜结构的十级光学存储单元 incoPat
专利 | 2023-05-10 | CN202310524570.X
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一种硫系相变材料结合Ag纳米颗粒多层薄膜结构的十级光学存储单元,属于光学存储领域。存储单元包括基底、记录层、反射层和保护层。Ag纳米颗粒的引入改变了纳秒脉冲激光辐照存储单元时记录层的热分布和热传输,显著影响了记录层的微观组织结构。通过改变纳秒激光能量密度,可以获得差值较大的十个光学反射率值,进而实现了十级光学存储。此外,存储单元还具有良好的可循环性。本发明通过相变材料的热稳定性和非易失性,结合纳秒激光的普遍性,摆脱了传统意义上的二值存储,实现了光学大密度存储。同时,所设计结构简单,制备快捷,可以大量投入生产,为未来全光存储、计算的发展奠定了基础。

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GB/T 7714 刘富荣 , 马全龙 , 陈清远 et al. 一种硫系相变材料结合Ag纳米颗粒多层薄膜结构的十级光学存储单元 : CN202310524570.X[P]. | 2023-05-10 .
MLA 刘富荣 et al. "一种硫系相变材料结合Ag纳米颗粒多层薄膜结构的十级光学存储单元" : CN202310524570.X. | 2023-05-10 .
APA 刘富荣 , 马全龙 , 陈清远 , 饶凯 , 张露露 . 一种硫系相变材料结合Ag纳米颗粒多层薄膜结构的十级光学存储单元 : CN202310524570.X. | 2023-05-10 .
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Effect of Thermal Cycling on Grain Evolution and Micro-Segregation in Selective Laser Melting of FGH96 Superalloy SCIE
期刊论文 | 2023 , 13 (1) | METALS
WoS CC Cited Count: 8
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Abstract :

Extremely rapid heating and cooling rates during the additive manufacturing (AM) process generate complicated thermal cycles, which affect the microstructure evolution and ultimate mechanical properties of the alloy. In this paper, FGH96 blocks with a height of 6 mm were prepared by selective laser melting (SLM) and the microstructure was characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Comparing specimens of varying heights, it was found that subsequent thermal cycles (STC) coarsened some solidified grains and accelerated the grain growth along the build direction, together with an increase in texture intensity and high-angle grain boundaries (HAGBs). After coarsening the grains in the middle portion of the built block, finer grains were observed near the top area due to a faster cooling rate. There were numerous dislocations in the grain because of the occurrence of unequal internal tension. In the middle of the sample with stable thermal cycles, the dislocations were both perpendicular to the grain growth direction and 45 degrees off it. In spite of the texture characteristics, the segregation of elements was also found to be influenced by thermal cycling. Inherent reheating leads to the increase in the Laves phase and the decrease in the gamma' phase as subsequent deposition. This was also one of the reasons why the microhardness of the sample decreased as the building height and the other reason being the decrease in the solution treatment of the later sediments.

Keyword :

thermal cycles thermal cycles micro-segregation micro-segregation microstructure evolution microstructure evolution selective laser melting selective laser melting

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GB/T 7714 Li, Lin , Liu, Furong , Nie, Shijin et al. Effect of Thermal Cycling on Grain Evolution and Micro-Segregation in Selective Laser Melting of FGH96 Superalloy [J]. | METALS , 2023 , 13 (1) .
MLA Li, Lin et al. "Effect of Thermal Cycling on Grain Evolution and Micro-Segregation in Selective Laser Melting of FGH96 Superalloy" . | METALS 13 . 1 (2023) .
APA Li, Lin , Liu, Furong , Nie, Shijin , Wang, Qin , Zhao, Rongxia , Zhang, Yongzhi et al. Effect of Thermal Cycling on Grain Evolution and Micro-Segregation in Selective Laser Melting of FGH96 Superalloy . | METALS , 2023 , 13 (1) .
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Stacked Ge2Sb2Te5/Indium Tin Oxide Nanoscale-Thick Interference Units for Increased Saturation Reflective Colors and Shortwave Infrared Shielding SCIE
期刊论文 | 2022 | ACS APPLIED NANO MATERIALS
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Abstract :

Fabry-Perot structures comprising metal/interference medium/metal have attracted considerable attention as lithography-free and scalable color reflectors, as such structures can selectively absorb electromagnetic waves in the visible range to produce vivid reflected colors. However, traditional methods for producing high-saturation reflected colors generally use a narrow full width at half-maximum (fwhm) or high reflectivity. This work proposes a nanoscale multi-unit-stacking structure based on a Ge2Sb2Te5 (GST)-ITO interference unit to obtain high-saturation colors combined with fwhm and reflectivity. Finite element simulations and experimental measurements reveal that the additional absorption bands introduced by the stacking interference units reduce the fwhm of the peak and increase reflectivity, thus improving the saturation. Furthermore, adjustments in the number of stacking cells lead to changes in the saturation but have a negligible effect on the hue. The use of germanium-antimony-tellurium (also denoted as GST) as a phase-change material can facilitate further adjustments in the optical tenability of the structure upon phase transition, indicating certain potential applications. Moreover, the structure exhibits shortwave infrared shielding owing to the destructive interference of the GST layer. Additionally, the application of this structure in color printing was demonstrated. This study simplifies the design process of highly saturated colors, circumvents expensive preparation processes, and offers the possibility of shortwave infrared shielding. The nanoscale structures described herein indicate new opportunities in the field of color coatings, intelligent windows, and decorations.

Keyword :

interference unit interference unit Fabry-Perot reflector Fabry-Perot reflector infrared shielding infrared shielding phase-change materials phase-change materials gamut gamut

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GB/T 7714 Chen, Qingyuan , Liu, Furong , Zhang, Yongzhi et al. Stacked Ge2Sb2Te5/Indium Tin Oxide Nanoscale-Thick Interference Units for Increased Saturation Reflective Colors and Shortwave Infrared Shielding [J]. | ACS APPLIED NANO MATERIALS , 2022 .
MLA Chen, Qingyuan et al. "Stacked Ge2Sb2Te5/Indium Tin Oxide Nanoscale-Thick Interference Units for Increased Saturation Reflective Colors and Shortwave Infrared Shielding" . | ACS APPLIED NANO MATERIALS (2022) .
APA Chen, Qingyuan , Liu, Furong , Zhang, Yongzhi , Zhang, Lulu , Lian, Yangbo , Yin, Boshuo . Stacked Ge2Sb2Te5/Indium Tin Oxide Nanoscale-Thick Interference Units for Increased Saturation Reflective Colors and Shortwave Infrared Shielding . | ACS APPLIED NANO MATERIALS , 2022 .
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一种基于波导光栅结构的非易失性十进制光电存储器 incoPat
专利 | 2021-08-27 | CN202110997579.3
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一种基于波导光栅结构的非易失性十进制光电存储器,属于信息技术领域。存储器包括层底、光波导、导电极材料和相变材料薄膜。相变材料薄膜呈阵列光栅式结构沉积在波导上,通过电信号可以改变相变材料薄膜的状态,编程调控晶态和非晶态的个数,就可以将数据写入/擦除在光栅阵列中。相变材料薄膜在晶态和非晶态的光学常数存在巨大差异,可以改变光波导中的光传播行为。于是,利用光信号的透过率不同就可以读出写入的数据。本发明相变材料的非易失性超快相变特性,并结合电驱动的普适性和光读取的超快性,实现存储器的低损耗和大容量,同时,所设计结构简单,便于集成,为未来光电器件的发展奠定了基础。

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GB/T 7714 刘富荣 , 张露露 , 张永志 et al. 一种基于波导光栅结构的非易失性十进制光电存储器 : CN202110997579.3[P]. | 2021-08-27 .
MLA 刘富荣 et al. "一种基于波导光栅结构的非易失性十进制光电存储器" : CN202110997579.3. | 2021-08-27 .
APA 刘富荣 , 张露露 , 张永志 , 陈清远 , 谢轩轩 , 连阳波 . 一种基于波导光栅结构的非易失性十进制光电存储器 : CN202110997579.3. | 2021-08-27 .
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一种基于多效应光学干涉的防伪薄膜及其制备方法 incoPat
专利 | 2021-08-16 | CN202110934288.X
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一种基于多效应光学干涉的防伪薄膜及其制备方法涉及薄膜材料和光学防伪领域。薄膜包括:载体层(211)、基材层(212)、预干涉介质层(22)、功能层(231)、保护层(232),其中,以基材层和预干涉介质层组成的干涉单元结构可以周期多次叠加。其中,该薄膜的制备是通过控制磁控溅射的转盘的转速和停/转,控制干涉介质层面的均匀性,以得到多效应复合干涉的防伪薄膜。本发明的防伪薄膜,通过非传统溅射工艺附着到工件表面后,可根据观察到制品表面不同的色彩变化,呈现出绚丽多彩的效果。此外。可以通过改变结构的各层材料及其厚度来获得多种特定色彩,实现对光学电磁波干涉的自由调控,防伪性能强,也适用多种场景下的不同需求。

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GB/T 7714 刘富荣 , 陈清远 , 张永志 et al. 一种基于多效应光学干涉的防伪薄膜及其制备方法 : CN202110934288.X[P]. | 2021-08-16 .
MLA 刘富荣 et al. "一种基于多效应光学干涉的防伪薄膜及其制备方法" : CN202110934288.X. | 2021-08-16 .
APA 刘富荣 , 陈清远 , 张永志 , 谢轩轩 , 李林 , 张露露 et al. 一种基于多效应光学干涉的防伪薄膜及其制备方法 : CN202110934288.X. | 2021-08-16 .
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一种基于旋转参量控制的多功能彩色防伪薄膜制备方法 incoPat
专利 | 2021-08-24 | CN202110978063.4
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一种基于旋转参量控制的多功能彩色防伪薄膜制备方法,涉及薄膜材料和光学防伪领域。包括:干涉介质层,复合于所述干涉介质层底部的基底层,以及复合于所述干涉介质层顶部的表面膜层;其中,所述基底层包括基材层,以及将所述基材层附着于其上的载体层;所述表面膜层包括复合于上述干涉介质层顶部的功能层,以及将复合于所述功能层顶部的保护层。其中,通过改变传统磁控溅射制备工艺,控制溅射时转盘周期及角度等,改变传统工艺,突破常规固态芯片式防伪设计,提高标识的外观表现力;亚波长量级的厚度也使标识的设计及应用场景更加灵活。

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GB/T 7714 刘富荣 , 陈清远 , 张永志 et al. 一种基于旋转参量控制的多功能彩色防伪薄膜制备方法 : CN202110978063.4[P]. | 2021-08-24 .
MLA 刘富荣 et al. "一种基于旋转参量控制的多功能彩色防伪薄膜制备方法" : CN202110978063.4. | 2021-08-24 .
APA 刘富荣 , 陈清远 , 张永志 , 张家威 , 魏文聪 , 李林 et al. 一种基于旋转参量控制的多功能彩色防伪薄膜制备方法 : CN202110978063.4. | 2021-08-24 .
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一种基于相变材料调控的Y分支波导结构偏振分束器 incoPat
专利 | 2021-08-28 | CN202110999127.9
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一种基于相变材料调控的Y分支波导结构偏振分束器,属于光器件应用和信息处理技术领域。偏振分束器包括基底、Y分支光波导和相变材料薄膜。相变材料薄膜分别呈单层上贴式和两个单层侧贴式沉积在Y分支波导上,通过波导中的倏逝场耦合作用可以改变相变材料薄膜的状态,调整混合光波导的尺寸可以将TM/TE偏振模式分离输出。相变材料薄膜在晶态和非晶态的光学常数存在巨大差异,可以改变光波导中的光传播行为。利用有效折射率的不同就可以实现偏振态输出和截止。本发明基于Si波导和相变材料的非易失性超快相变偏振分束器,实现器件的低损耗和微型化,设计结构简单,便于集成,为未来全光器件的发展奠定了基础。

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GB/T 7714 刘富荣 , 谢轩轩 , 张永志 et al. 一种基于相变材料调控的Y分支波导结构偏振分束器 : CN202110999127.9[P]. | 2021-08-28 .
MLA 刘富荣 et al. "一种基于相变材料调控的Y分支波导结构偏振分束器" : CN202110999127.9. | 2021-08-28 .
APA 刘富荣 , 谢轩轩 , 张永志 , 陈清远 , 张露露 , 连阳波 . 一种基于相变材料调控的Y分支波导结构偏振分束器 : CN202110999127.9. | 2021-08-28 .
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Effect of structure architecture on optical properties of TiTe2/Sb2Te3 multilayer nanofilms SCIE
期刊论文 | 2021 , 877 | JOURNAL OF ALLOYS AND COMPOUNDS
WoS CC Cited Count: 4
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Abstract :

Heterostructural materials have the advantage of extreme low switching energy between states and hence are expected to be applied in photonic devices, whose optical performances are vital to explore in advance. In this paper, crystal structures of TiTe2/Sb2Te3 heterostructural films and their effects on optical properties were clarified from the aspects of in-plane strain, resonant bonding and charge redistribution by experiments and first principle simulations. Larger strain in Sb2Te3 sublayer tended to decrease reflectivity and refractive indexes, while huge resonant bonding effect was beneficial to improve the optical parameter deviations. Charge analyses showed that crystalline optical property variations were actually deriving from the electron redistribution differences especially near the heterostructural Te center dot center dot center dot Te gap, which also accounted for experimental reflectivity order. Finally, based on the resonant bond effects and surrounding electron density after stimuluses, five optical levels with identifiable optical contrasts (n and Delta R) were achieved in 1/2 model for uses. The present study sheds new light on optical properties of TiTe2/Sb2Te3 and paves the way for potential multi-state applications of heterostructure in photonic and storage devices. (C) 2021 Elsevier B.V. All rights reserved.

Keyword :

First principle simulation First principle simulation Optical properties Optical properties Heterostructure Heterostructure Charge distribution Charge distribution

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GB/T 7714 Han, Gang , Liu, Furong , Zhang, Yongzhi et al. Effect of structure architecture on optical properties of TiTe2/Sb2Te3 multilayer nanofilms [J]. | JOURNAL OF ALLOYS AND COMPOUNDS , 2021 , 877 .
MLA Han, Gang et al. "Effect of structure architecture on optical properties of TiTe2/Sb2Te3 multilayer nanofilms" . | JOURNAL OF ALLOYS AND COMPOUNDS 877 (2021) .
APA Han, Gang , Liu, Furong , Zhang, Yongzhi , Li, Jingwen , Li, Wenqiang , Chen, Qingyuan et al. Effect of structure architecture on optical properties of TiTe2/Sb2Te3 multilayer nanofilms . | JOURNAL OF ALLOYS AND COMPOUNDS , 2021 , 877 .
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Control of ferromagnetic resonance by phase change in Si/GeSbTe/ FeCoB heterostructures SCIE
期刊论文 | 2021 , 538 | JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
WoS CC Cited Count: 2
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Phase-change materials (PCMs) provide an alternative avenue for modulating the adjacent layer property through interfacial effect, which sometimes is more effective than the traditional methods. Here, a systematic study of the phase-change induced control of FMR resonance field in Si/GeSbTe/FeCoB heterostructures is presented. We show that different crystalline phases induced by thermal anneal in GeSbTe/FeCoB films contribute to large shifts in resonance field of FeCoB up to 15 mT. The correlation between GeSbTe phase change and anisotropic field of FeCoB is confirmed from the GeSbTe film morphology dependent of stress. These results propose a method of phase-change induced control of FMR resonant field and ferromagnetism in PCM/ferromagnetic alloy film heterostructures by controlling interface roughness, which can be introduced in the optimization of ferromagnetic alloy film parameters and development of high functioning magnetic devices.

Keyword :

Heterostructures Heterostructures Phase-change material Phase-change material Ferromagnetic resonance Ferromagnetic resonance Annealing Annealing

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GB/T 7714 Wei, Yuyi , Wang, Jiawei , Wang, Xinjun et al. Control of ferromagnetic resonance by phase change in Si/GeSbTe/ FeCoB heterostructures [J]. | JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS , 2021 , 538 .
MLA Wei, Yuyi et al. "Control of ferromagnetic resonance by phase change in Si/GeSbTe/ FeCoB heterostructures" . | JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS 538 (2021) .
APA Wei, Yuyi , Wang, Jiawei , Wang, Xinjun , Chen, Huaihao , Yu, Chengju , He, Yifan et al. Control of ferromagnetic resonance by phase change in Si/GeSbTe/ FeCoB heterostructures . | JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS , 2021 , 538 .
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