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作者:

Xu, Peng (Xu, Peng.) | Wu, Zhixing (Wu, Zhixing.) | Deng, Jiguang (Deng, Jiguang.) | Liu, Yuxi (Liu, Yuxi.) | Xie, Shaohua (Xie, Shaohua.) | Guo, Guangsheng (Guo, Guangsheng.) | Dai, Hongxing (Dai, Hongxing.) (学者:戴洪兴)

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EI Scopus SCIE PKU CSCD

摘要:

Ordered mesoporous Mn2O3 (meso-Mn2O3) and meso-Mn2O3-supported Pd, Pt, and Pd-Pt alloy x(PdyPt)/meso-Mn2O3; x = (0.10-1.50) wt%; Pd/Pt molar ratio (y) = 4.9-5.1 nanocatalysts were prepared using KIT-6-templated and poly(vinyl alcohol)-protected reduction methods, respectively. The meso-Mn2O3 had a high surface area, i.e., 106 m(2)/g, and a cubic crystal structure. Noble-metal nanoparticles (NPs) of size 2.1-2.8 nm were uniformly dispersed on the meso-Mn2O3 surfaces. Alloying Pd with Pt enhanced the catalytic activity in methane combustion; 1.41(Pd5.1Pt)/meso-Mn2O3 gave the best performance; T-10%,T- T-50%,T- and T-90% (the temperatures required for achieving methane conversions of 10%, 50%, and 90%) were 265, 345, and 425 degrees C, respectively, at a space velocity of 20000 mL/(g.h). The effects of SO2, CO2, H2O, and NO on methane combustion over 1.41(Pd5.1Pt)/meso-Mn2O3 were also examined. We conclude that the good catalytic performance of 1.41(Pd5.1Pt)/meso-Mn2O3 is associated with its high-quality porous structure, high adsorbed oxygen species concentration, good low-temperature reducibility, and strong interactions between Pd-Pt alloy NPs and the meso-Mn2O3 support. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

关键词:

Ordered mesoporous manganese oxide Supported noble metal catalyst Strong metal-support interaction Methane combustion Pd-Pt alloy nanoparticle

作者机构:

  • [ 1 ] [Guo, Guangsheng]Beijing Univ Technol, Coll Environm & Energy Engn,Educ Minist China, Dept Chem & Chem Engn,Key Lab Adv Functional Mat, Beijing Key Lab Green Catalysis & Separat,Key Lab, Beijing 100124, Peoples R China
  • [ 2 ] [Guo, Guangsheng]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Chem & Chem Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China
  • [ 3 ] [Dai, Hongxing]Beijing Univ Technol, Coll Environm & Energy Engn,Educ Minist China, Dept Chem & Chem Engn,Key Lab Adv Functional Mat, Beijing Key Lab Green Catalysis & Separat,Key Lab, Beijing 100124, Peoples R China
  • [ 4 ] [Dai, Hongxing]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Chem & Chem Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China

通讯作者信息:

  • 戴洪兴

    [Guo, Guangsheng]Beijing Univ Technol, Coll Environm & Energy Engn,Educ Minist China, Dept Chem & Chem Engn,Key Lab Adv Functional Mat, Beijing Key Lab Green Catalysis & Separat,Key Lab, Beijing 100124, Peoples R China;;[Dai, Hongxing]Beijing Univ Technol, Coll Environm & Energy Engn,Educ Minist China, Dept Chem & Chem Engn,Key Lab Adv Functional Mat, Beijing Key Lab Green Catalysis & Separat,Key Lab, Beijing 100124, Peoples R China

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来源 :

CHINESE JOURNAL OF CATALYSIS

ISSN: 0253-9837

年份: 2017

期: 1

卷: 38

页码: 92-105

1 6 . 5 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:212

中科院分区:2

被引次数:

WoS核心集被引频次: 38

SCOPUS被引频次: 39

ESI高被引论文在榜: 0 展开所有

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