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作者:

Ma, Delong (Ma, Delong.) | Shi, Xiaomin (Shi, Xiaomin.) | Hu, Anming (Hu, Anming.)

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摘要:

A strategy for growth of porous Ni2GeO4 nanosheets on conductive nickel (Ni) foam with robust adhesion as a high-performance electrode for Li-ion batteries is proposed and realized, through a facile two-step method. It involves the low temperature hydro-thermal synthesis of bimetallic (Ni, Ge) hydroxide nanosheets precursor on Ni foam substrates and subsequent thermal transformation to porous Ni2GeO4 nanosheets. The as-prepared Ni2GeO4 nanosheets possess many interparticle mesopores with a size range from 5 to 15 nm. The hierarchical structure of porous Ni2GeO4 nanosheets supported by Ni foam promises fast electron and ion transport, large electroactive surface area, and excellent structural stability. The efficacy of the specially designed structure is demonstrated by the superior electrochemical performance of the generated Ni2GeO4 nanosheets including a high capacity of 1.8 m.A.hcm(-2) at a current density of 50 mu Acm(-2), good cycle stability, and high power capability at room temperature. Because of simple conditions, this fabrication strategy may be easily extended to other mixed metal oxides (MxGeOy).

关键词:

porous nanosheets Li-ion batteries Ni2GeO4 Self-standing Ni foam

作者机构:

  • [ 1 ] [Ma, Delong]Beijing Univ Technol, Inst Laser Engn, 100 Pingle Yuan, Beijing 100124, Peoples R China
  • [ 2 ] [Shi, Xiaomin]Beijing Univ Technol, Inst Laser Engn, 100 Pingle Yuan, Beijing 100124, Peoples R China
  • [ 3 ] [Hu, Anming]Beijing Univ Technol, Inst Laser Engn, 100 Pingle Yuan, Beijing 100124, Peoples R China
  • [ 4 ] [Ma, Delong]Univ Tennessee Knoxville, Dept Mech Aerosp & Biomed Engn, 1512 Middle Dr, Knoxville, TN 37996 USA
  • [ 5 ] [Hu, Anming]Univ Tennessee Knoxville, Dept Mech Aerosp & Biomed Engn, 1512 Middle Dr, Knoxville, TN 37996 USA

通讯作者信息:

  • [Hu, Anming]Beijing Univ Technol, Inst Laser Engn, 100 Pingle Yuan, Beijing 100124, Peoples R China;;[Hu, Anming]Univ Tennessee Knoxville, Dept Mech Aerosp & Biomed Engn, 1512 Middle Dr, Knoxville, TN 37996 USA

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来源 :

NANOMATERIALS

年份: 2016

期: 11

卷: 6

5 . 3 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:305

中科院分区:3

被引次数:

WoS核心集被引频次: 14

SCOPUS被引频次: 10

ESI高被引论文在榜: 0 展开所有

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