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摘要:
The anticorrosion mechanism of Al-Ti-Si-RE coating in the environment of simulated deep sea was investigated using electrochemical measurement and micro-analysis. The result shows that Al-Ti-Si-RE coating possesses better corrosion resistance at hydrostatic pressure than at atmospheric pressure. After 480 h immersion at 3 MPa, a platform similar to a passivation region occurs in the anode of the potentiodynamic polarization curve because corrosion products block the corrosion channels. At the same time, at hydrostatic pressure, electrochemical impedance spectroscopy (EIS) indicates that Al passive film dissolves within 6 h of immersion, then tends to be stable after 12 h, and hardly changes between 300 and 480 h. To further analyze the original corrosion process, electrochemical noise (EN) of 0 similar to 64 ks at 0.1 and 3 MPa was measured, which quantificationally described the corrosion process from passive film dissolving to corrosion product fast-forming to stabilization. From morphology observation and X-ray diffraction (XRD) analysis, the rich Ti phase (Ti-Al intermetallics, etc) of the coating is cellular and has good corrosion resistance, whose construction could fix the Al oxide inside the coating, and thicken the coating to inhibit the corrosion.
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来源 :
RARE METAL MATERIALS AND ENGINEERING
ISSN: 1002-185X
年份: 2016
期: 11
卷: 45
页码: 2918-2924
0 . 7 0 0
JCR@2022
ESI学科: MATERIALS SCIENCE;
ESI高被引阀值:305
中科院分区:4
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