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作者:

Tong Hui (Tong Hui.) | Wei Shicheng (Wei Shicheng.) | Liu Yi (Liu Yi.) | Wang Xinkun (Wang Xinkun.) | Liu Wenchao (Liu Wenchao.) | Xu Binshi (Xu Binshi.) (学者:徐滨士)

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EI Scopus SCIE PKU CSCD

摘要:

The anticorrosion mechanism of Al-Ti-Si-RE coating in the environment of simulated deep sea was investigated using electrochemical measurement and micro-analysis. The result shows that Al-Ti-Si-RE coating possesses better corrosion resistance at hydrostatic pressure than at atmospheric pressure. After 480 h immersion at 3 MPa, a platform similar to a passivation region occurs in the anode of the potentiodynamic polarization curve because corrosion products block the corrosion channels. At the same time, at hydrostatic pressure, electrochemical impedance spectroscopy (EIS) indicates that Al passive film dissolves within 6 h of immersion, then tends to be stable after 12 h, and hardly changes between 300 and 480 h. To further analyze the original corrosion process, electrochemical noise (EN) of 0 similar to 64 ks at 0.1 and 3 MPa was measured, which quantificationally described the corrosion process from passive film dissolving to corrosion product fast-forming to stabilization. From morphology observation and X-ray diffraction (XRD) analysis, the rich Ti phase (Ti-Al intermetallics, etc) of the coating is cellular and has good corrosion resistance, whose construction could fix the Al oxide inside the coating, and thicken the coating to inhibit the corrosion.

关键词:

coating deep sea corrosion electrochemical measurements high velocity arc spraying micro-analysis

作者机构:

  • [ 1 ] [Tong Hui]Beijing Univ Technol, Beijing 100124, Peoples R China
  • [ 2 ] [Tong Hui]Acad Armored Forces Engn, Natl Key Lab Remfg, Beijing 100072, Peoples R China
  • [ 3 ] [Wei Shicheng]Acad Armored Forces Engn, Natl Key Lab Remfg, Beijing 100072, Peoples R China
  • [ 4 ] [Liu Yi]Acad Armored Forces Engn, Natl Key Lab Remfg, Beijing 100072, Peoples R China
  • [ 5 ] [Wang Xinkun]Acad Armored Forces Engn, Natl Key Lab Remfg, Beijing 100072, Peoples R China
  • [ 6 ] [Liu Wenchao]Acad Armored Forces Engn, Natl Key Lab Remfg, Beijing 100072, Peoples R China
  • [ 7 ] [Xu Binshi]Acad Armored Forces Engn, Natl Key Lab Remfg, Beijing 100072, Peoples R China

通讯作者信息:

  • [Wei Shicheng]Acad Armored Forces Engn, Natl Key Lab Remfg, Beijing 100072, Peoples R China

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来源 :

RARE METAL MATERIALS AND ENGINEERING

ISSN: 1002-185X

年份: 2016

期: 11

卷: 45

页码: 2918-2924

0 . 7 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:198

中科院分区:4

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