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Author:

Xin, Hongxing (Xin, Hongxing.) | Zhu, Xiaohe (Zhu, Xiaohe.) | Yan, Hong (Yan, Hong.) (Scholars:闫红) | Song, Xiuqing (Song, Xiuqing.)

Indexed by:

Scopus SCIE

Abstract:

The reactions of 1,4-diazabutadienes 1 with HClO4 were studied in detail. The final products obtained were not the hydroperchlorates of 1 but imidazolium perchlorates 2 or 3. A possible reaction process is postulated on the basis of the isolation of the intermediate 2-iminomethylimidazolium salt 4. The factors influencing the conversion of 4 to the imidazolium perchlorates 2 and 3 were discussed with regard to the electronic and steric effects of the N-substituents. This reaction can serve as an approach for the synthesis of imidazolium derivatives.

Keyword:

Author Community:

  • [ 1 ] [Xin, Hongxing]Beijing Univ Technol, Coll Life Sci & Bioengn, Pingleyuan St 100, Beijing 100124, Peoples R China
  • [ 2 ] [Zhu, Xiaohe]Beijing Univ Technol, Coll Life Sci & Bioengn, Pingleyuan St 100, Beijing 100124, Peoples R China
  • [ 3 ] [Yan, Hong]Beijing Univ Technol, Coll Life Sci & Bioengn, Pingleyuan St 100, Beijing 100124, Peoples R China
  • [ 4 ] [Song, Xiuqing]Beijing Univ Technol, Coll Life Sci & Bioengn, Pingleyuan St 100, Beijing 100124, Peoples R China

Reprint Author's Address:

  • 闫红

    [Yan, Hong]Beijing Univ Technol, Coll Life Sci & Bioengn, Pingleyuan St 100, Beijing 100124, Peoples R China

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Source :

JOURNAL OF HETEROCYCLIC CHEMISTRY

ISSN: 0022-152X

Year: 2016

Issue: 5

Volume: 53

Page: 1363-1366

2 . 4 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:221

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 2

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 7

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