(Li0.06Na0.47K0.47)NbO3　(LNKN)　ceramics　with　0-2　mol%　V2O5　has　been　prepared　following　the　conventional　solid　state　sintering　method　without　cold-isostatic　pressing　(CIP)　process.　The　effects　of　V2O5　addition　on　the　sinterability　and　electrical　properties　of　the　LNKN　ceramics　were　examined.　Solid　solution　limit　of　V2O5　in　LNKN　is　thought　to　be　around　1　mol%.　1　mol%　V2O5　addition　is　effective　in　decreasing　the　sinter　temperature　and　increasing　the　density　of　LNKN　to　95.3%　of　the　theoretical　density　of　LNKN　ceramic　(4.47　g/cm(3)),　while　the　optimized　electrical　properties,　such　as　epsilon(r)=493,　tan　delta=0.014,　d(33)=207　pC/N　and　k(p)=0.43,　are　obtained.