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In this paper, Cu2ZnSnS4 (CZTS) solar cells absorber layers and Cu2ZnSn(SxSe1-x) 4 (CZTSSe) with the S/Se ratio varying between 0 and 1 were prepared by an isopropanol-based solution method. The S/Se ratio dependence of photovoltaic properties have been systematically investigated and the performance of the CZTS-based solar cells has been improved by the optimization process. This research would be helpful for the development of cost effective solution-processed CZTSSe thin film solar cells.
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