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作者:

Li Song-Hao (Li Song-Hao.) | Zhang Xin (Zhang Xin.) | Liu Hong-Liang (Liu Hong-Liang.) | Zheng Liang (Zheng Liang.) | Zhang Jiu-Xing (Zhang Jiu-Xing.)

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Scopus SCIE PKU CSCD

摘要:

SnSe material is one of the most promising state-of-art thermoelectric materials. The polycrystalline Ag-doped Sn1-xAgxSe (0.005 <= x <= 0.03) bulks were prepared by mechanical alloying and spark plasma sintering technique, and the composition, microstructure and thermoelectric properties were systematically studied by XRD, SEM and thermoelectric performance measurement. XRD results show that single-phase orthorhombic SnSe-based compounds can be prepared with small amount of Ag-doping (0.005 <= x <= 0.01), but with Ag doping amount increasing, small quantity of secondary phase, SnAgSe2, can be detected in the matrix. The carrier concentration and overall electrical properties (power factor) are significantly enhanced as a result of Ag doping. The power factor of Sn0.98Ag0.02Se increases up to 0.495x10(-3) W/(m.K-2), which is about 36% higher than that of SnSe material. Although the thermal conductivity increases slightly, the dimensionless figure of merit, ZT is still optimized for the Ag-doped samples. Sn0.98Ag0.02Se bulk shows optimal ZT value and the highest ZT of 0.82 is obtained at 823 K, which is the highest value reported for the polycrystalline SnSe-based thermoelectric materials.

关键词:

Ag-doped SnSe Spark plasma sintering thermoelectric property

作者机构:

  • [ 1 ] [Li Song-Hao]Beijing Univ technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Educ Minist, Beijing 100124, Peoples R China
  • [ 2 ] [Zhang Xin]Beijing Univ technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Educ Minist, Beijing 100124, Peoples R China
  • [ 3 ] [Liu Hong-Liang]Beijing Univ technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Educ Minist, Beijing 100124, Peoples R China
  • [ 4 ] [Zheng Liang]Beijing Univ technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Educ Minist, Beijing 100124, Peoples R China
  • [ 5 ] [Zhang Jiu-Xing]Beijing Univ technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Educ Minist, Beijing 100124, Peoples R China
  • [ 6 ] [Zhang Jiu-Xing]Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Peoples R China

通讯作者信息:

  • [Li Song-Hao]Beijing Univ technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Educ Minist, Beijing 100124, Peoples R China

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来源 :

JOURNAL OF INORGANIC MATERIALS

ISSN: 1000-324X

年份: 2016

期: 7

卷: 31

页码: 751-755

1 . 7 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:198

中科院分区:4

被引次数:

WoS核心集被引频次: 1

SCOPUS被引频次: 2

ESI高被引论文在榜: 0 展开所有

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