Binuclear　iron　phthalocyanine/reduced　graphene　oxide　(bi-FePc/RGO)　nanocomposite　with　good　electrocatalytic　activity　for　ORR　in　alkaline　medium　was　prepared　in　one　step.　High　angle　annular　dark　field　image　scanning　transmission　electron　microscopy　(HAADF-STEM)　and　energy　dispersive　X-ray　spectroscopy　element　mapping　results　show　bi-FePc　was　uniformly　distributed　on　RGO.　An　obvious　cathodic　peak　located　at　about-0.23　V　(vs.　SCE)　in　CV　and　an　onset　potential　of-0.004　V　(vs.　SCE)　in　LSV　indicate　the　as-prepared　bi-FePc/RGO　nanocomposite　possesses　high　activity　which　is　closed　to　Pt/C　for　ORR.　The　ORR　on　bi-FePc/RGO　nanocomposite　follows　four-electron　transfer　pathway　in　alkaline　medium.　Compared　with　Pt/C,　there　is　only　a　slight　decrease　(about　0.02　V　vs.　SCE)　for　bi-FePc/RGO　nanocomposite　when　the　methanol　exists.　The　excellent　activity　and　methanol　tolerance　in　alkaline　solutions　proves　that　bi-FePc/RGO　nanocomposite　could　be　considered　as　a　promising　cathode　catalyst　for　alkaline　fuel　cells.