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作者:

Zhang Yanzhuo (Zhang Yanzhuo.) | Li Jun (Li Jun.) | Chen Guanghui (Chen Guanghui.) | Bian Wei (Bian Wei.) | Lu Yun (Lu Yun.) | Li Wenjing (Li Wenjing.) | Zheng Zhaoming (Zheng Zhaoming.) | Cheng Xiaojie (Cheng Xiaojie.)

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摘要:

The high colority and difficulty of decolorization are the most important tasks on printing and dyeing wastewater. This study investigates the ability of diatomite earth&carbon (DE&C) as an adsorbent to removal crystal violet (CV) from aqueous solutions. Fourier transform infrared spectroscopy results indicate the importance of functional groups during the adsorption of CV. The obtained N-2 adsorption-desorption isotherm values accord with well IUPAC type II. Our calculations determined a surface area of 73.15 m(2) g(-1) for DE&C and an average pore diameter of 10.56 nm. Equilibrium data of the adsorption process fitted very well to the Langmuir model (R-2>0.99). The results of kinetics study showed that the pseudo-second-order model fitted to the experimental data well. The thermodynamic parameters were also evaluated. Delta H degrees <0, Delta S degrees >0 and Delta G degrees <0 demonstrated that the adsorption process was spontaneous and exothermic for dye. Furthermore the positive value of Delta S degrees reflected good affinity of the CV dye.

关键词:

crystal violet adsorption hydrothermal carbonization diatomite earth&carbon

作者机构:

  • [ 1 ] [Zhang Yanzhuo]Beijing Univ Technol, Key Lab Beijing Water Qual Sci & Water Environm R, Coll Architecture & Civil Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Li Jun]Beijing Univ Technol, Key Lab Beijing Water Qual Sci & Water Environm R, Coll Architecture & Civil Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Chen Guanghui]Beijing Univ Technol, Key Lab Beijing Water Qual Sci & Water Environm R, Coll Architecture & Civil Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Bian Wei]Beijing Univ Technol, Key Lab Beijing Water Qual Sci & Water Environm R, Coll Architecture & Civil Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Lu Yun]Beijing Univ Technol, Key Lab Beijing Water Qual Sci & Water Environm R, Coll Architecture & Civil Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Li Wenjing]Beijing Univ Technol, Key Lab Beijing Water Qual Sci & Water Environm R, Coll Architecture & Civil Engn, Beijing 100124, Peoples R China
  • [ 7 ] [Zheng Zhaoming]Beijing Univ Technol, Key Lab Beijing Water Qual Sci & Water Environm R, Coll Architecture & Civil Engn, Beijing 100124, Peoples R China
  • [ 8 ] [Cheng Xiaojie]Beijing Univ Technol, Key Lab Beijing Water Qual Sci & Water Environm R, Coll Architecture & Civil Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • [Zhang Yanzhuo]Beijing Univ Technol, Key Lab Beijing Water Qual Sci & Water Environm R, Coll Architecture & Civil Engn, Beijing 100124, Peoples R China

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来源 :

WATER SCIENCE AND TECHNOLOGY

ISSN: 0273-1223

年份: 2016

期: 6

卷: 73

页码: 1463-1471

2 . 7 0 0

JCR@2022

ESI学科: ENVIRONMENT/ECOLOGY;

ESI高被引阀值:246

中科院分区:4

被引次数:

WoS核心集被引频次: 4

SCOPUS被引频次: 4

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

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