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摘要:
The high colority and difficulty of decolorization are the most important tasks on printing and dyeing wastewater. This study investigates the ability of diatomite earth&carbon (DE&C) as an adsorbent to removal crystal violet (CV) from aqueous solutions. Fourier transform infrared spectroscopy results indicate the importance of functional groups during the adsorption of CV. The obtained N-2 adsorption-desorption isotherm values accord with well IUPAC type II. Our calculations determined a surface area of 73.15 m(2) g(-1) for DE&C and an average pore diameter of 10.56 nm. Equilibrium data of the adsorption process fitted very well to the Langmuir model (R-2>0.99). The results of kinetics study showed that the pseudo-second-order model fitted to the experimental data well. The thermodynamic parameters were also evaluated. Delta H degrees <0, Delta S degrees >0 and Delta G degrees <0 demonstrated that the adsorption process was spontaneous and exothermic for dye. Furthermore the positive value of Delta S degrees reflected good affinity of the CV dye.
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来源 :
WATER SCIENCE AND TECHNOLOGY
ISSN: 0273-1223
年份: 2016
期: 6
卷: 73
页码: 1463-1471
2 . 7 0 0
JCR@2022
ESI学科: ENVIRONMENT/ECOLOGY;
ESI高被引阀值:246
中科院分区:4