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A numerical simulation has been conducted to investigate the heat and mass transfer in the adsorption process of an annular cavity bed. The silica gel and the water was taken as the working pair. The 2D model of the heat and mass transfer has been established for the adsorption problem. To clarify the cooling effect of different situations, the air cooling mode and the water cooling mode were considered to apply onto the bed. Based on the numerical results the change of the temperature and the vapor concentration of the bed was analyzed and discussed. The influence of the bed layer porosity and the evaporation temperature on the performance was examined too. The results have revealed that the bed temperature increased largely at the first 400 seconds of the adsorption time. This time corresponded to the rapid adsorption and the large amount of the heat generation. Beyond a summit, the temperature of the bed decreased gradually while the bed concentration kept increasing. The bed layer porosity affected the adsorption only in a small scale, while increasing the evaporation temperature promoted the adsorption largely.
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