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作者:

Liu, Z. Y. (Liu, Z. Y..) | Zhang, F. P. (Zhang, F. P..) | Zhang, J. X. (Zhang, J. X..) | Zhang, X. (Zhang, X..) | Lu, Q. M. (Lu, Q. M..) | Yang, X. Y. (Yang, X. Y..)

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Scopus SCIE

摘要:

The powders as well as the texture modulated Ca2.8BaxPryCo4O9+delta (x, y = 0, 0.05, 0.1, 0.15 and 0.2) bulk materials are prepared via solid state reaction, sol-gel and spark plasma sintering method. The powder and bulk materials are analyzed with regard to their phase composition and microscopic character by X-ray diffraction (XRD) and scanning electron microscope (SEM). The thermoelectric transport properties of the bulk materials are measured and investigated. The results show that the plate-like powders with uniform particle size tend to align regularly rather than the powders with anomaly shape and particle size distribution by spark plasma sintering method. The bulk materials co-doped by elements with lower electronegativity tend to form better texture rather than that of the bulk materials co-doped by elements with higher electronegativity via spark plasma sintering method. The resistivities and Seebeck coefficients are in negative accordance to the bulk material texture as a whole, and the carrier transport mechanism is not influenced. The electrical performance is tuned with optimized power factor 462 mu Wm(-1) K-2 at 973 K for Ca2.8BaxPryCo4O9+delta (x = y = 0.1) bulk materials. (C) 2016 The Authors. Published by Elsevier B.V.

关键词:

Ca3Co4O9+delta Co-doping Texture modulation Thermoelectric properties

作者机构:

  • [ 1 ] [Liu, Z. Y.]Henan Normal Univ, Coll Phys & Elect Engn, Henan Key Lab Photovolta Mat, Xinxiang 453007, Peoples R China
  • [ 2 ] [Zhang, F. P.]Henan Univ Urban Construct, Henan Prov Ctr Phys Properties Simulat, Inst Appl Phys, Pingdingshan 467036, Henan, Peoples R China
  • [ 3 ] [Zhang, F. P.]Beijing Univ Technol, Coll Mat Sci & Engn, Natl Key Lab Adv Funct Mat, Chinese Minist Educ, Beijing 100124, Peoples R China
  • [ 4 ] [Zhang, J. X.]Beijing Univ Technol, Coll Mat Sci & Engn, Natl Key Lab Adv Funct Mat, Chinese Minist Educ, Beijing 100124, Peoples R China
  • [ 5 ] [Zhang, X.]Beijing Univ Technol, Coll Mat Sci & Engn, Natl Key Lab Adv Funct Mat, Chinese Minist Educ, Beijing 100124, Peoples R China
  • [ 6 ] [Lu, Q. M.]Beijing Univ Technol, Coll Mat Sci & Engn, Natl Key Lab Adv Funct Mat, Chinese Minist Educ, Beijing 100124, Peoples R China
  • [ 7 ] [Zhang, J. X.]Hefei Univ Technol, Sch Mat Sci & Engn, Anhui Prov Key Lab Adv Funct Mat & Devices, Hefei 230009, Peoples R China
  • [ 8 ] [Yang, X. Y.]Hefei Univ Technol, Sch Mat Sci & Engn, Anhui Prov Key Lab Adv Funct Mat & Devices, Hefei 230009, Peoples R China

通讯作者信息:

  • [Zhang, F. P.]Beijing Univ Technol, Coll Mat Sci & Engn, Natl Key Lab Adv Funct Mat, Chinese Minist Educ, Beijing 100124, Peoples R China

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来源 :

RESULTS IN PHYSICS

ISSN: 2211-3797

年份: 2016

卷: 6

页码: 203-208

5 . 3 0 0

JCR@2022

中科院分区:4

被引次数:

WoS核心集被引频次: 8

SCOPUS被引频次: 10

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