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作者:

Chu, Biwu (Chu, Biwu.) | Liu, Yongchun (Liu, Yongchun.) | Ma, Qingxin (Ma, Qingxin.) | Ma, Jinzhu (Ma, Jinzhu.) | He, Hong (He, Hong.) (学者:何洪) | Wang, Gang (Wang, Gang.) | Cheng, Shuiyuan (Cheng, Shuiyuan.) (学者:程水源) | Wang, Xinming (Wang, Xinming.)

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摘要:

In order to evaluate the secondary aerosol formation potential at a suburban site of Beijing, in situ perturbation experiments in a potential aerosol mass (PAM) reactor were carried out in the winter of 2014. The variations of secondary aerosol formation as a function of time, OH exposure, and the concentrations of gas phase pollutants and particles were reported in this study. Two periods with distinct secondary aerosol formation potentials, marked as Period I and Period II, were identified during the observation. In Period I, the secondary aerosol formation potential was high, and correlated well to the air pollutants, i. e., SO2, NO2, and CO. The maximal secondary aerosol formation was observed with an aging time equivalent to about 3 days of atmospheric oxidation. In period II, the secondary aerosol formation potential was low, with no obvious correlation with the air pollutants. Meanwhile, the aerosol mass decreased, instead of showing a peak, with increasing aging time. Backward trajectory analysis during the two periods confirmed that the air mass in Period I was mainly from local sources, while it was attributed mostly to long distance transport in Period II. The air lost its reactivity during the long transport and the particles became highly aged, resulting in a low secondary aerosol formation potential. Our experimental results indicated that the in situ measurement of the secondary aerosol formation potential could provide important information for evaluating the contributions of local emission and long distance transport to the aerosol pollution. (C) 2015 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.

关键词:

Aging In situ perturbation experiments Local emission Long distance transport Potential aerosol mass

作者机构:

  • [ 1 ] [Chu, Biwu]Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Joint Lab Environm Simulat & Pollut Con, Beijing 100085, Peoples R China
  • [ 2 ] [Liu, Yongchun]Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Joint Lab Environm Simulat & Pollut Con, Beijing 100085, Peoples R China
  • [ 3 ] [Ma, Qingxin]Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Joint Lab Environm Simulat & Pollut Con, Beijing 100085, Peoples R China
  • [ 4 ] [Ma, Jinzhu]Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Joint Lab Environm Simulat & Pollut Con, Beijing 100085, Peoples R China
  • [ 5 ] [He, Hong]Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Joint Lab Environm Simulat & Pollut Con, Beijing 100085, Peoples R China
  • [ 6 ] [Wang, Gang]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100022, Peoples R China
  • [ 7 ] [Cheng, Shuiyuan]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100022, Peoples R China
  • [ 8 ] [Wang, Xinming]Chinese Acad Sci, Guangzhou Inst Geochem, State Key Lab Organ Geochem, Guangzhou 510640, Guangdong, Peoples R China

通讯作者信息:

  • 何洪

    [He, Hong]Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Joint Lab Environm Simulat & Pollut Con, Beijing 100085, Peoples R China

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来源 :

JOURNAL OF ENVIRONMENTAL SCIENCES

ISSN: 1001-0742

年份: 2016

卷: 39

页码: 52-61

6 . 9 0 0

JCR@2022

ESI学科: ENVIRONMENT/ECOLOGY;

ESI高被引阀值:145

中科院分区:3

被引次数:

WoS核心集被引频次: 12

SCOPUS被引频次: 15

ESI高被引论文在榜: 0 展开所有

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