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作者:

Zhao, Hong-Wu (Zhao, Hong-Wu.) | Li, Bo (Li, Bo.) | Tian, Ting (Tian, Ting.) | Song, Xiu-Qing (Song, Xiu-Qing.) | Pang, Hai-Liang (Pang, Hai-Liang.) | Chen, Xiao-Qin (Chen, Xiao-Qin.) | Yang, Zhao (Yang, Zhao.) | Meng, Wei (Meng, Wei.)

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Scopus SCIE

摘要:

In the presence of 10 mol% of Na2CO3, the desired imidazolidine-spirooxindoles were obtained in 81-99% yield with up to 99 : 1 dr by means of the diastereoselective [3 + 2] cycloaddition of N-acylhydrazine-derived imines with 3-isothiocyanato oxindoles. Single-crystal X-ray structure analysis was conducted to determine the relative stereochemistry of the imidazolidine-spirooxindoles. Diastereoselective access to the imidazolidine-spirooxindoles was hypothesized by the proposed mechanism.

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作者机构:

  • [ 1 ] [Zhao, Hong-Wu]Beijing Univ Technol, Coll Life Sci & Bioengn, 100 Pingleyuan, Beijing 100124, Peoples R China
  • [ 2 ] [Li, Bo]Beijing Univ Technol, Coll Life Sci & Bioengn, 100 Pingleyuan, Beijing 100124, Peoples R China
  • [ 3 ] [Tian, Ting]Beijing Univ Technol, Coll Life Sci & Bioengn, 100 Pingleyuan, Beijing 100124, Peoples R China
  • [ 4 ] [Song, Xiu-Qing]Beijing Univ Technol, Coll Life Sci & Bioengn, 100 Pingleyuan, Beijing 100124, Peoples R China
  • [ 5 ] [Pang, Hai-Liang]Beijing Univ Technol, Coll Life Sci & Bioengn, 100 Pingleyuan, Beijing 100124, Peoples R China
  • [ 6 ] [Chen, Xiao-Qin]Beijing Univ Technol, Coll Life Sci & Bioengn, 100 Pingleyuan, Beijing 100124, Peoples R China
  • [ 7 ] [Yang, Zhao]Beijing Univ Technol, Coll Life Sci & Bioengn, 100 Pingleyuan, Beijing 100124, Peoples R China
  • [ 8 ] [Meng, Wei]Beijing Univ Technol, Coll Life Sci & Bioengn, 100 Pingleyuan, Beijing 100124, Peoples R China

通讯作者信息:

  • [Zhao, Hong-Wu]Beijing Univ Technol, Coll Life Sci & Bioengn, 100 Pingleyuan, Beijing 100124, Peoples R China

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来源 :

RSC ADVANCES

ISSN: 2046-2069

年份: 2016

期: 33

卷: 6

页码: 27690-27695

3 . 9 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:221

中科院分区:3

被引次数:

WoS核心集被引频次: 10

SCOPUS被引频次: 10

ESI高被引论文在榜: 0 展开所有

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