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作者:

Si, Guanhao (Si, Guanhao.) | Xi, Xiaoli (Xi, Xiaoli.) (学者:席晓丽) | Nie, Zuoren (Nie, Zuoren.) (学者:聂祚仁) | Zhang, Liwen (Zhang, Liwen.) | Ma, Liwen (Ma, Liwen.)

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摘要:

Tungsten carbide (WC) scrap was used as a consumable anode to prepare tungsten powder in NaCl-KCl melt at 1023 K for the first time. The electrolysis process was investigated. Results showed that the tungsten component in WC anode was dissolved as W2+ into the NaCl-KCl melt. The cathode reaction was controlled by the diffusion of tungsten ions. The effect of electrolysis parameters, including the anode-cathode distance, cathode current density and different electrolysis ways (galvanostatic and potentiostatic electrolysis), on the purity and grain size of the cathode deposits was studied. It showed that a large anode-cathode distance was beneficial to the formation of pure tungsten powder at the cathode. With increasing the cathode current density, the tungsten grain size first decreased and then increased. When the cathode current density was 0.125 A cm(-2), tungsten powder with a diameter of smaller than 100 nm was obtained. Deposits prepared through galvanostatic and potentiostatic electrolysis was compared in the end. (C) 2015 Elsevier Ltd. All rights reserved.

关键词:

Electrolysis Preparation Tungsten powder WC scrap

作者机构:

  • [ 1 ] [Si, Guanhao]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Xi, Xiaoli]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Nie, Zuoren]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Zhang, Liwen]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Ma, Liwen]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • 席晓丽

    [Xi, Xiaoli]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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来源 :

INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS

ISSN: 0263-4368

年份: 2016

卷: 54

页码: 422-426

3 . 6 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:198

中科院分区:2

被引次数:

WoS核心集被引频次: 20

SCOPUS被引频次: 22

ESI高被引论文在榜: 0 展开所有

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