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作者:

Zhang, Yanzhuo (Zhang, Yanzhuo.) | Li, Jun (Li, Jun.) | Li, Wenjing (Li, Wenjing.)

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EI Scopus SCIE

摘要:

This study investigated how the particle size of the modified adsorbent diatomite earth & chitosan (DE&C) affects the removal of sunset yellow (SY) from water using a fixed bed column. Fourier Transform Infrared Spectroscopy (FTIR) analysis indicated that the amino group (-NH2) played an important role during the adsorption of SY. The calculated surface area of the DE&C absorbent was found to be 69.68 m(2) g(-1) and SEM images showed that DE&C is a superior porous adsorbent. Four dimensions of DE&C were measured in a fixed bed column. The breakthrough time of SY increased as the size of DE&C decreased and the effluent concentration showed a trend of first increasing and then decreasing. It was also found that the nature of the variation in the effluent concentration with time was parabolic and that the adsorption data fitted the parabolic equation at C-t/C-0 = 0-0.1. Due to the different combination ability with hydrogen bonding, the phenomenon of parabolic variation is quite disparate from other adsorbents. But, compared with the breakthrough time, the saturation time was close to other particle sizes, except for 2.86-3.35 mm in size. pH is an important parameter for the adsorption of SY and the main mechanism is adsorption with each other between positive and negative charges. The Thomas model shows lower correlation with the smaller sizes and R-2 with an average of 0.9413. The Thomas model indicated that the maximum value of q(0) was 97.06 mg g(-1) and with an increase in the initial SY concentration, the bed height and the values of q(0) decreased as k(t) increased. The Yoon-Nelson model describing the theoretical required time was close to the experimental values and k(YN) increased as C-0 increased.

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作者机构:

  • [ 1 ] [Zhang, Yanzhuo]Beijing Univ Technol, Coll Architecture & Civil Engn, Key Lab Beijing Water Qual Sci & Water Environm R, Beijing 100124, Peoples R China
  • [ 2 ] [Li, Jun]Beijing Univ Technol, Coll Architecture & Civil Engn, Key Lab Beijing Water Qual Sci & Water Environm R, Beijing 100124, Peoples R China
  • [ 3 ] [Li, Wenjing]Beijing Univ Technol, Coll Architecture & Civil Engn, Key Lab Beijing Water Qual Sci & Water Environm R, Beijing 100124, Peoples R China

通讯作者信息:

  • [Zhang, Yanzhuo]Beijing Univ Technol, Coll Architecture & Civil Engn, Key Lab Beijing Water Qual Sci & Water Environm R, Beijing 100124, Peoples R China

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RSC ADVANCES

ISSN: 2046-2069

年份: 2015

期: 104

卷: 5

页码: 85673-85681

3 . 9 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:179

JCR分区:2

中科院分区:3

被引次数:

WoS核心集被引频次: 18

SCOPUS被引频次: 18

ESI高被引论文在榜: 0 展开所有

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