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摘要:
By considering the functionality of junctions and entanglements of polymer chains for polyelectrolyte gels, a new free energy density function is presented via combining Edwards-Vilgis slip-link model with Flory-Huggins theory. On this basis, the effects of the functionality of network junctions and entanglements of polymer chains are systematically analyzed for free swelling of a cubic polyelectrolyte gel and constrained swelling of a blanket layer of the gel. Analytical results show that the functionality of junctions and chains entanglements plays an important role in the coupled chemomechanical deformation of polyelectrolyte gels.
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来源 :
ADVANCES IN CONDENSED MATTER PHYSICS
ISSN: 1687-8108
年份: 2015
卷: 2015
1 . 5 0 0
JCR@2022
ESI学科: PHYSICS;
ESI高被引阀值:190
JCR分区:4
中科院分区:4