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作者:

Wang Chao (Wang Chao.) | Chen Jing (Chen Jing.) | Chen Hong-Li (Chen Hong-Li.) | Hou Yu-Dong (Hou Yu-Dong.) (学者:侯育冬) | Zhu Man-Kang (Zhu Man-Kang.)

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EI Scopus SCIE PKU CSCD

摘要:

Using average 30 nm grain sized potassium sodium niobate powders obtained by a novel Sol-Gel method as starting materials, nanocrystalline potassium sodium niobate ceramics with pure orthorhombic phase, relative density of above 99% and grain size of 40 nm were prepared by spark plasma sintering method under sintering temperature of 900 degrees C, sintering pressure of 30 MPa and sintering time of 1 min. The phase structure, micro-morphology, dielectric properties and ferroelectric properties of the ceramics were investigated. The results show that, differently from common micro-grain ceramics, dielectric constant of nanocrystalline potassium sodium niobate ceramics decreases to 341, which changes little with the temperature, and the ceramics have obvious dielectric relaxation (dispersion factor gamma is 1.60), and a well saturated ferroelectric hysteresis loop with coercive field of 13.5 kV/cm and remanent polarization of 1.5 mu C/cm(2). The abnormal properties can be attributed to the significant increasing content of grain boundary in nanocrystalline potassium sodium niobate ceramics, and it can be expected that if potassium sodium niobate ceramic has the critical size at room temperature, it would be less than 40 nm.

关键词:

dielectric relaxation ferroelectric hysteresis loop nanocrystalline ceramic potassium sodium niobate

作者机构:

  • [ 1 ] [Wang Chao]Beijing Wuzi Univ, Logist Sch, Beijing 101149, Peoples R China
  • [ 2 ] [Chen Jing]Beijing Wuzi Univ, Logist Sch, Beijing 101149, Peoples R China
  • [ 3 ] [Chen Hong-Li]Beijing Wuzi Univ, Logist Sch, Beijing 101149, Peoples R China
  • [ 4 ] [Hou Yu-Dong]Beijing Univ Technol, Key Lab Adv Funct Mat, China Educ Minist, Beijing 100124, Peoples R China
  • [ 5 ] [Zhu Man-Kang]Beijing Univ Technol, Key Lab Adv Funct Mat, China Educ Minist, Beijing 100124, Peoples R China

通讯作者信息:

  • [Wang Chao]Beijing Wuzi Univ, Logist Sch, Beijing 101149, Peoples R China

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来源 :

JOURNAL OF INORGANIC MATERIALS

ISSN: 1000-324X

年份: 2015

期: 1

卷: 30

页码: 59-64

1 . 7 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:224

JCR分区:3

中科院分区:4

被引次数:

WoS核心集被引频次: 5

SCOPUS被引频次:

ESI高被引论文在榜: 0 展开所有

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