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作者:

Yang, Yilong (Yang, Yilong.) | Li, Yongli (Li, Yongli.) | Wang, Jinshu (Wang, Jinshu.) (学者:王金淑) | Zhang, Yan (Zhang, Yan.) | He, Di (He, Di.) | Wu, Junshu (Wu, Junshu.) | Dai, Hongxing (Dai, Hongxing.) (学者:戴洪兴)

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EI Scopus SCIE

摘要:

Nitrogen-doped TiO2-bronze@g-C3N4 (TiO2 (B)@g-C3N4) two-dimensional binary heterojunctions were constructed based on seeding-induced growth through a microwave-assisted solvothermal process and subsequent thermal treatment in a vacuum. The morphology of the TiO2 (B) nanosheets could be controlled by tuning the concentration of the Ti precursor, which determined the enhanced photoelectron activity. The optimal photocatalytic activity for the degradation of methyl orange (MO) under low-intensity visible-light illumination was obtained at a TiO2 (B)/g-C3N4 molar ratio of 1 : 1, which was 12.7 and 7.9 times higher than that of pure g-C3N4 and P25, respectively. The photocatalytic activity was further enhanced by about 7.7% after in situ N-doping. The improvement in photocatalytic activity of N-doped TiO2 (B)@g-C3N4 hetero-nanojunctions was attributable to the strong absorption in the visible-light region and better separation of photogenerated electron-hole pairs at the nanojunction interface, a result due to the large contact area between N-doped TiO2 (B) and g-C3N4 nanosheets. We have explained the photocatalytic degradation of MO molecules largely in terms of the direct oxidation by the photogenerated holes and partly by the contribution of the superoxide radicals.

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作者机构:

  • [ 1 ] [Yang, Yilong]Beijing Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Beijing 100124, Peoples R China
  • [ 2 ] [Li, Yongli]Beijing Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Beijing 100124, Peoples R China
  • [ 3 ] [Wang, Jinshu]Beijing Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Beijing 100124, Peoples R China
  • [ 4 ] [Zhang, Yan]Beijing Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Beijing 100124, Peoples R China
  • [ 5 ] [He, Di]Beijing Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Beijing 100124, Peoples R China
  • [ 6 ] [Wu, Junshu]Beijing Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Beijing 100124, Peoples R China
  • [ 7 ] [Dai, Hongxing]Beijing Univ Technol, Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 8 ] [Dai, Hongxing]Beijing Univ Technol, Lab Catalysis Chem & Nanosci, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • [Yang, Yilong]Beijing Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Beijing 100124, Peoples R China

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来源 :

RSC ADVANCES

年份: 2015

期: 63

卷: 5

页码: 50833-50842

3 . 9 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:179

JCR分区:2

中科院分区:3

被引次数:

WoS核心集被引频次: 10

SCOPUS被引频次: 10

ESI高被引论文在榜: 0 展开所有

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