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摘要:
Cathodic protection is usually used to control the corrosion in service pipeline. The optimum cathodic protection potential (OCPP) becomes a vital part in order to get the best protective effect in the whole research of cathodic protection. Up to now, depending on experience, the OCPP is often defined between 200mV to 300mV more electronegative than the free corrosion potential under usual circumstances (neutral aqueous solution or soil). However, the phenomena of over-protection and under-protection usually occur in service pipeline with the complexity of soil environment. The cathodic protection parameters of X100 pipeline steel in Dagang, Daqing and Lasa simulated soil solutions have been investigated by using the polarization test and electrochemical impedance spectroscopy (EIS). The value of R-t (the charge transfer resistance) by analyzing EIS curves showed that the polarization resistance of the specimen had a maximum value with negative shift of the polarization potential. If the value was negative to 1000 Omega center dot cm(2), the hydrogen evolution reaction would occur. The potential of hydrogen evolution in the three simulated soil solutions from low to high was Dagang, Daqing and Lasa. This research could offer theoretical guideline and technique support for the cathodic protection of pipeline steel.
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来源 :
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
ISSN: 1452-3981
年份: 2014
期: 12
卷: 9
页码: 7660-7671
1 . 5 0 0
JCR@2022
ESI学科: CHEMISTRY;
ESI高被引阀值:258
JCR分区:3
中科院分区:4
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