Eight　silver(I)　complexes　containing　DPEphos　(bis[2-(diphenylphosphino)phenyl]ether)　and　dppe　(bis　(diphenylphosphino)ethane),　namely　[Ag2Cl2(DPEphos)(2)(dppe)](CH3OH)(2)(DMF)　(1),　[Ag2Br2(DPEphos)(2)]　(DMF)(2)　(2),　[AB(2)(OTf)(2)(DPEphos)(2)(dPPe)]　(3)　(OTf　=　trifluoromethanesulfonate),　[Ag-2(NO3)(2)(DPEphos)(2)　(dppe)]　(4),　[Ag(DPEphos)(dppe)](OTf)　(5),　[Ag(NO3)(DPEphos)]　(6),　[Ag(NO2)(DPEphos)]　(7)　and　[Ag(DPEphos)(dppe)](BF4)　(8),　have　been　synthesized.　They　were　characterized　by　IR　spectroscopy,　X-ray　diffraction,　RT　luminescence,　H-1　and　P-31　NMR　spectroscopy.　Complexes　5-8　were　obtained　in　the　mixed　solvents　of　CH3OH　and　CH2Cl2,　while　1-4　were　obtained　in　the　mixed　solvents　of　CH3OH,　CH2Cl2　and　DMF　(DMF　=　N,N-dimethylformamide).　Complexes　1-4　display　dinuclear　structures,　in　which　two　silver　atoms　are　bridged　by　one　dppe　ligand　(for　1,3　and　4)　or　two　Br　atoms　(for　2).　The　other　four　are　mononuclear　complexes.　The　P-31　NMR　spectra　of　the　title　compounds　are　measured,　each　spectrum　shows　rich　signals　which　belong　to　P　atoms　in　different　chemical　environment.　In　the　P-31　NMR　spectra,　there　exist　splitting　signals　(doublets　or　triplets)　which　can　be　attributed　to　the　coupling　of　the　Ag-107,Ag-109-P-31　or　F-19-P-31,　where　the　coupling　of　F-19-P-31　was　found　for　the　first　time　in　silver(I)-P　complexes　containing　OTf-　or　BF4-　anions.　(C)　2014　Elsevier　Ltd.　All　rights　reserved.