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作者:

Zhang, Yujuan (Zhang, Yujuan.) | Deng, Jiguang (Deng, Jiguang.) | Zhang, Lei (Zhang, Lei.) | Dai, Hongxing (Dai, Hongxing.) (学者:戴洪兴)

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Scopus SCIE PKU CSCD

摘要:

High-surface-area and well-ordered mesoporous Fe-incorporated SBA-15 (xFe-SBA-15) and SBA-15-supported FeO (x) (yFeO (x) /SBA-15) with the Fe surface density between 0.09 to 1.11 Fe-atom/nm(2) have been prepared using the one-step synthesis and incipient wetness impregnation methods, respectively. Physicochemical properties of these materials were characterized by means of numerous techniques, and their catalytic activities for the combustion of toluene were evaluated. It is found that the xFe-SBA-15 and yFeO (x) /SBA-15 samples possessed rod- or chain-like morphologies. The Fe species were of high dispersion when the Fe surface density was lower than 0.76 Fe-atom/nm(2) in xFe-SBA-15 and 0.64 Fe-atom/nm(2) in yFeO (x) /SBA-15. At a similar Fe surface density and space velocity, the xFe-SBA-15 catalysts showed better activity than the yFeO (x) /SBA-15 catalysts, in which the xFe-SBA-15 catalyst with Fe surface density 0.59 Fe-atom/nm(2) performed the best. It is concluded that the good performance of the xFe-SBA-15 sample with Fe surface density 0.59 Fe-atom/nm(2) was associated with its large surface area, high Fe species dispersion, and good low-temperature reducibility.

关键词:

Iron-incorporated SBA-15 Low-temperature reducibility SBA-15-supported iron oxide Toluene combustion

作者机构:

  • [ 1 ] [Zhang, Yujuan]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China
  • [ 2 ] [Deng, Jiguang]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China
  • [ 3 ] [Zhang, Lei]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China
  • [ 4 ] [Dai, Hongxing]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China

通讯作者信息:

  • 邓积光

    [Deng, Jiguang]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China

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来源 :

CHINESE SCIENCE BULLETIN

ISSN: 1001-6538

年份: 2014

期: 31

卷: 59

页码: 3993-4002

JCR分区:2

中科院分区:3

被引次数:

WoS核心集被引频次: 10

SCOPUS被引频次: 11

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

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