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[期刊论文]

Recovery of rare earth elements from waste fluorescent phosphors: Na2O2 molten salt decomposition

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Author:

Wu, Yufeng (Wu, Yufeng.) (Scholars:吴玉锋) | Wang, Baolei (Wang, Baolei.) | Zhang, Qijun (Zhang, Qijun.) | Unfold

Indexed by:

CPCI-S EI Scopus SCIE

Abstract:

In this paper, an efficient recovery of rare earth elements from waste fluorescent phosphors has been reported and the novel process of alkali fusion and acid leaching has been proposed. The experimental results have shown that the key for efficient recycling is the complete dissolution of waste fluorescent phosphors. The Na2O2-to-waste mass ratio, calcination temperature and reactive time play considerable roles in rare earth elements extraction during the alkali fusion process. The optimal conditions in terms of temperature, time and Na2O2-to-waste mass ratio are 650 A degrees C, 15 min and 2:1, respectively, under which more than 99.5 % rare earth elements are extracted. The possible reaction mechanism of alkali fusion has been proposed.

Keyword:

Waste fluorescent phosphors Leaching efficiency Rare earth Alkali fusion

Author Community:

  • [ 1 ] [Wu, Yufeng]Beijing Univ Technol, Inst Recycling Econ, Beijing 100124, Peoples R China
  • [ 2 ] [Wang, Baolei]Beijing Univ Technol, Inst Recycling Econ, Beijing 100124, Peoples R China
  • [ 3 ] [Zhang, Qijun]Beijing Univ Technol, Inst Recycling Econ, Beijing 100124, Peoples R China
  • [ 4 ] [Li, Ruiqing]Beijing Univ Technol, Inst Recycling Econ, Beijing 100124, Peoples R China
  • [ 5 ] [Wang, Wei]Beijing Univ Technol, Inst Recycling Econ, Beijing 100124, Peoples R China
  • [ 6 ] [Sun, Chenghua]Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China

Reprint Author's Address:

  • [Zhang, Qijun]Beijing Univ Technol, Inst Recycling Econ, Beijing 100124, Peoples R China

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Related Article:

Source :

JOURNAL OF MATERIAL CYCLES AND WASTE MANAGEMENT

ISSN: 1438-4957

Year: 2014

Issue: 4

Volume: 16

Page: 635-641

3 . 1 0 0

JCR@2022

ESI Discipline: ENVIRONMENT/ECOLOGY;

ESI HC Threshold:309

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 22

SCOPUS Cited Count: 28

30 Days PV: 4

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