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作者:

Fei, Huilong (Fei, Huilong.) | Ye, Ruquan (Ye, Ruquan.) | Ye, Gonglan (Ye, Gonglan.) | Gong, Yongji (Gong, Yongji.) | Peng, Zhiwei (Peng, Zhiwei.) | Fan, Xiujun (Fan, Xiujun.) | Samuel, Errol L. G. (Samuel, Errol L. G..) | Ajayan, Pulickel M. (Ajayan, Pulickel M..) | Tour, James M. (Tour, James M..)

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EI Scopus SCIE

摘要:

The scarcity and high cost of platinum-based electrocatalysts for the oxygen reduction reaction (ORR) has limited the commercial and scalable use of fuel cells. Heteroatom-doped nanocarbon materials have been demonstrated to be efficient alternative catalysts for ORR. Here, graphene quantum dots, synthesized from inexpensive and earth-abundant anthracite coal, were self-assembled on graphene by hydrothermal treatment to form hybrid nanoplatelets that were then codoped with nitrogen and boron by high-temperature annealing. This hybrid material combined the advantages of both components, such as abundant edges and doping sites, high electrical conductivity, and high surface area, which makes the resulting materials excellent oxygen reduction electrocatalysts with activity even higher than that of commercial Pt/C in alkaline media.

关键词:

boron nitrogen doping coal electrocatalyst graphene quantum dots oxygen reduction reaction

作者机构:

  • [ 1 ] [Fei, Huilong]Rice Univ, Dept Chem, Houston, TX 77005 USA
  • [ 2 ] [Ye, Ruquan]Rice Univ, Dept Chem, Houston, TX 77005 USA
  • [ 3 ] [Gong, Yongji]Rice Univ, Dept Chem, Houston, TX 77005 USA
  • [ 4 ] [Peng, Zhiwei]Rice Univ, Dept Chem, Houston, TX 77005 USA
  • [ 5 ] [Samuel, Errol L. G.]Rice Univ, Dept Chem, Houston, TX 77005 USA
  • [ 6 ] [Ajayan, Pulickel M.]Rice Univ, Dept Chem, Houston, TX 77005 USA
  • [ 7 ] [Tour, James M.]Rice Univ, Dept Chem, Houston, TX 77005 USA
  • [ 8 ] [Fan, Xiujun]Rice Univ, Smalley Inst Nanoscale Sci & Technol, Houston, TX 77005 USA
  • [ 9 ] [Tour, James M.]Rice Univ, Smalley Inst Nanoscale Sci & Technol, Houston, TX 77005 USA
  • [ 10 ] [Ye, Gonglan]Rice Univ, Dept Mat Sci & NanoEngn, Houston, TX 77005 USA
  • [ 11 ] [Ajayan, Pulickel M.]Rice Univ, Dept Mat Sci & NanoEngn, Houston, TX 77005 USA
  • [ 12 ] [Tour, James M.]Rice Univ, Dept Mat Sci & NanoEngn, Houston, TX 77005 USA
  • [ 13 ] [Fan, Xiujun]Beijing Univ Technol, Coll Elect Informat & Control Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • [Ajayan, Pulickel M.]Rice Univ, Dept Chem, 6100 Main St, Houston, TX 77005 USA

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来源 :

ACS NANO

ISSN: 1936-0851

年份: 2014

期: 10

卷: 8

页码: 10837-10843

1 7 . 1 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:195

JCR分区:1

中科院分区:1

被引次数:

WoS核心集被引频次: 392

SCOPUS被引频次: 414

ESI高被引论文在榜: 17 展开所有

  • 2022-3
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  • 2018-11

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