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摘要:
Magnetic refrigeration based on the magnetocaloric effect offers a potential energy saving, atmosphere friendly way to replace vapor-compression refrigeration. In this work, Mn1.2Fe0.8P0.74Ge0.26-xSex (x=0, 0.005, 0.01, 0.015, 0.02, 0.03) compounds were prepared by mechanical milling and subsequent spark plasma sintering (SPS) technique, their crystal structures, phase transition process and magnetocaloric properties were investigated by XRD, DSC, VSM and direct measurement equipment of magnetocaloric effect. The results show that the Mn1.2Fe0.8P0.74Ge0.26-.xSex compounds possess a hexagonal Fe2P-type crystal structure. With increasing Se concentration, the lattice parameters a and c change significantly. It causes c/a ratio decreases firstly, keeps unchanging and followed by increasing again. And the Curie temperature (T-c) of the compounds is increased with the decrease of the c/a ratio. Either applied magnetic field or temperature change can induce the magnetic transformation between the paramagnetic phase and ferromagnetic phase. Low substitution of Se for Ge (x <= 0.015) in the Mn1.2Fe0.8P0.74Ge0.26-xSex compounds leads to higher T-c, narrower temperature range of the two-phase coexistence (Delta T-coex) and larger adiabatic temperature change (Delta T-ad), in addition the thermal hysteresis (Delta T-hys) and entropy change (Delta S-DSC) remain almost unaffected. 0.01 Se substitution leads to 5.6 K increase in T-c,10.6% decrease in Delta T-coex, and 10% increase in Delta T-ad. With a further increase in Se content, magnetocaloric properties of compound decrease.
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来源 :
ACTA METALLURGICA SINICA
ISSN: 0412-1961
年份: 2014
期: 9
卷: 50
页码: 1109-1114
2 . 3 0 0
JCR@2022
ESI学科: MATERIALS SCIENCE;
ESI高被引阀值:341
JCR分区:3
中科院分区:4