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作者:

Wang Shaobo (Wang Shaobo.) | Liu Danmin (Liu Danmin.) (学者:刘丹敏) | Xiao Weiqiang (Xiao Weiqiang.) | Zhang Zhenlu (Zhang Zhenlu.) | Yue Ming (Yue Ming.) (学者:岳明) | Zhang Jiuxing (Zhang Jiuxing.)

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EI Scopus SCIE PKU CSCD

摘要:

Magnetic refrigeration based on the magnetocaloric effect offers a potential energy saving, atmosphere friendly way to replace vapor-compression refrigeration. In this work, Mn1.2Fe0.8P0.74Ge0.26-xSex (x=0, 0.005, 0.01, 0.015, 0.02, 0.03) compounds were prepared by mechanical milling and subsequent spark plasma sintering (SPS) technique, their crystal structures, phase transition process and magnetocaloric properties were investigated by XRD, DSC, VSM and direct measurement equipment of magnetocaloric effect. The results show that the Mn1.2Fe0.8P0.74Ge0.26-.xSex compounds possess a hexagonal Fe2P-type crystal structure. With increasing Se concentration, the lattice parameters a and c change significantly. It causes c/a ratio decreases firstly, keeps unchanging and followed by increasing again. And the Curie temperature (T-c) of the compounds is increased with the decrease of the c/a ratio. Either applied magnetic field or temperature change can induce the magnetic transformation between the paramagnetic phase and ferromagnetic phase. Low substitution of Se for Ge (x <= 0.015) in the Mn1.2Fe0.8P0.74Ge0.26-xSex compounds leads to higher T-c, narrower temperature range of the two-phase coexistence (Delta T-coex) and larger adiabatic temperature change (Delta T-ad), in addition the thermal hysteresis (Delta T-hys) and entropy change (Delta S-DSC) remain almost unaffected. 0.01 Se substitution leads to 5.6 K increase in T-c,10.6% decrease in Delta T-coex, and 10% increase in Delta T-ad. With a further increase in Se content, magnetocaloric properties of compound decrease.

关键词:

MnFePGeSe magnetocaloric effect magnetic phase transition

作者机构:

  • [ 1 ] [Wang Shaobo]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 2 ] [Liu Danmin]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 3 ] [Xiao Weiqiang]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 4 ] [Zhang Zhenlu]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 5 ] [Yue Ming]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Zhang Jiuxing]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • 刘丹敏

    [Liu Danmin]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China

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来源 :

ACTA METALLURGICA SINICA

ISSN: 0412-1961

年份: 2014

期: 9

卷: 50

页码: 1109-1114

2 . 3 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:341

JCR分区:3

中科院分区:4

被引次数:

WoS核心集被引频次: 4

SCOPUS被引频次:

ESI高被引论文在榜: 0 展开所有

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