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作者:

Lin, Jian (Lin, Jian.) | Ji, Heng (Ji, Heng.) | Swift, Michael W. (Swift, Michael W..) | Hardy, Will J. (Hardy, Will J..) | Peng, Zhiwei (Peng, Zhiwei.) | Fan, Xiujun (Fan, Xiujun.) | Nevidomskyy, Andriy H. (Nevidomskyy, Andriy H..) | Tour, James M. (Tour, James M..) | Natelson, Douglas (Natelson, Douglas.)

收录:

EI Scopus SCIE

摘要:

We report measurements of the diffusion of atomic hydrogen in single crystalline VO2 micro/nanobeams by direct exposure to atomic hydrogen, without catalyst. The atomic hydrogen is generated by a hot filament, and the doping process takes place at moderate temperature (373 K). Undoped VO2 has a metal-to-insulator phase transition at ?340 K between a high-temperature, rutile, metallic phase and a low-temperature, monoclinic, insulating phase with a resistance exhibiting a semiconductor-like temperature dependence. Atomic hydrogenation results in stabilization of the metallic phase of VO2 micro/nanobeams down to 2 K, the lowest point we could reach in our measurement setup. Optical characterization shows that hydrogen atoms prefer to diffuse along the c axis of rutile (a axis of monoclinic) VO2, along the oxygen channels. Based on observing the movement of the hydrogen diffusion front in single crystalline VO2 beams, we estimate the diffusion constant for hydrogen along the c axis of the rutile phase to be 6.7 x 1010 cm2/s at approximately 373 K, exceeding the value in isostructural TiO2 by ?38x. Moreover, we find that the diffusion constant along the c axis of the rutile phase exceeds that along the equivalent a axis of the monoclinic phase by at least 3 orders of magnitude. This remarkable change in kinetics must originate from the distortion of the channels when the unit cell doubles along this direction upon cooling into the monoclinic structure. Ab initio calculation results are in good agreement with the experimental trends in the relative kinetics of the two phases. This raises the possibility of a switchable membrane for hydrogen transport.

关键词:

Atomic Hydrogenation Hydrogen Diffusion MIT VO2

作者机构:

  • [ 1 ] [Lin, Jian]Rice Univ, Dept Mech Engn & Mat Sci, Houston, TX 77005 USA
  • [ 2 ] [Tour, James M.]Rice Univ, Dept Mech Engn & Mat Sci, Houston, TX 77005 USA
  • [ 3 ] [Lin, Jian]Rice Univ, Smalley Inst Nanoscale Sci & Technol, Houston, TX 77005 USA
  • [ 4 ] [Fan, Xiujun]Rice Univ, Smalley Inst Nanoscale Sci & Technol, Houston, TX 77005 USA
  • [ 5 ] [Tour, James M.]Rice Univ, Smalley Inst Nanoscale Sci & Technol, Houston, TX 77005 USA
  • [ 6 ] [Natelson, Douglas]Rice Univ, Smalley Inst Nanoscale Sci & Technol, Houston, TX 77005 USA
  • [ 7 ] [Ji, Heng]Rice Univ, Dept Phys & Astron, Houston, TX 77005 USA
  • [ 8 ] [Swift, Michael W.]Rice Univ, Dept Phys & Astron, Houston, TX 77005 USA
  • [ 9 ] [Hardy, Will J.]Rice Univ, Dept Phys & Astron, Houston, TX 77005 USA
  • [ 10 ] [Nevidomskyy, Andriy H.]Rice Univ, Dept Phys & Astron, Houston, TX 77005 USA
  • [ 11 ] [Natelson, Douglas]Rice Univ, Dept Phys & Astron, Houston, TX 77005 USA
  • [ 12 ] [Peng, Zhiwei]Rice Univ, Dept Chem, Houston, TX 77005 USA
  • [ 13 ] [Fan, Xiujun]Rice Univ, Dept Chem, Houston, TX 77005 USA
  • [ 14 ] [Tour, James M.]Rice Univ, Dept Chem, Houston, TX 77005 USA
  • [ 15 ] [Natelson, Douglas]Rice Univ, Dept Elect & Comp Engn, Houston, TX 77005 USA
  • [ 16 ] [Fan, Xiujun]Beijing Univ Technol, Coll Elect Informat & Control Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • [Natelson, Douglas]Rice Univ, Dept Phys & Astron, 6100 Main St, Houston, TX 77005 USA

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来源 :

NANO LETTERS

ISSN: 1530-6984

年份: 2014

期: 9

卷: 14

页码: 5445-5451

1 0 . 8 0 0

JCR@2022

ESI学科: PHYSICS;

ESI高被引阀值:151

JCR分区:1

中科院分区:1

被引次数:

WoS核心集被引频次: 55

SCOPUS被引频次: 61

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

近30日浏览量: 2

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