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作者:

Wang, Hong (Wang, Hong.) | Li, Hongyi (Li, Hongyi.) (学者:李洪义) | Wang, Jinshu (Wang, Jinshu.) (学者:王金淑) | Wu, Junshu (Wu, Junshu.) | Li, Dasheng (Li, Dasheng.) | Liu, Man (Liu, Man.) | Su, Penglei (Su, Penglei.)

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EI Scopus SCIE

摘要:

Power conversion efficiency of dye sensitized solar cell (DSSC) is closely related to photo-anode's structure. It has been believed that titanium dioxide (TiO2) nanotube array thin film is one of the best photo-anode candidates for DSSC. However, the insufficient internal surface area and wide band gap of pure anatase limit their power conversion efficiency. Here we report a novel TiO2 nanotube array film synthesized by anodization followed by surface modification with nitrogen (N) doped TiO2 nanoparticles using a solvothermal method. The incorporation of N doped TiO2 nanoparticles along the wall of TiO2 nanotubes not only provides a large surface area for dye loading, but also increases the conductivity of the electrode, generating an overall power conversion efficiency of 2.53%, which is 68% higher than that with pure TiO2 nanotube array (with the length of 1.8 mu m) photoanode. When the length of TiO2 nanotube increased to 4.1 mu m, the overall power conversion efficiency can be improved to be 4.9%, which is higher than the previous reported results using the same length of nanotube. (C) 2014 Elsevier Ltd. All rights reserved.

关键词:

doping DSSC surface modification TiO2 nanotube array

作者机构:

  • [ 1 ] [Wang, Hong]Beijing Univ Technol, Key Lab Adv Funct Mat, Sch Mat & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Li, Hongyi]Beijing Univ Technol, Key Lab Adv Funct Mat, Sch Mat & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Wang, Jinshu]Beijing Univ Technol, Key Lab Adv Funct Mat, Sch Mat & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Wu, Junshu]Beijing Univ Technol, Key Lab Adv Funct Mat, Sch Mat & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Li, Dasheng]Beijing Univ Technol, Key Lab Adv Funct Mat, Sch Mat & Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Liu, Man]Beijing Univ Technol, Key Lab Adv Funct Mat, Sch Mat & Engn, Beijing 100124, Peoples R China
  • [ 7 ] [Su, Penglei]Beijing Univ Technol, Key Lab Adv Funct Mat, Sch Mat & Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • 李洪义

    [Li, Hongyi]Beijing Univ Technol, Key Lab Adv Funct Mat, Sch Mat & Engn, Beijing 100124, Peoples R China

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来源 :

ELECTROCHIMICA ACTA

ISSN: 0013-4686

年份: 2014

卷: 137

页码: 744-750

6 . 6 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:195

JCR分区:1

中科院分区:1

被引次数:

WoS核心集被引频次: 35

SCOPUS被引频次: 35

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

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